About: Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: IV. Proton Transfer and Reactions of Dication Isomers in the CHCl2+ +D2 System.

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About: Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: IV. Proton Transfer and Reactions of Dication Isomers in the CHCl2+ +D2 System. Goto Sponge NotDistinct Permalink

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Description	Chemical reactions and charge transfer processes in the system CHCl2+ + D2 were investigated in crossed beam scattering experiments. Experimental data were complemented by theoretical calculations of the energetics of the species involved and by calculations of stationary points on the dication potential energy surfaces. The main reaction products were the cations CHCl+, CHDCl+, and CCl+. Integral cross sections for formation of these species were determined over the collision energy range 0.4-2.5 eV (center-of-mass, C.M.). Two isomers of the reactant dication were identified, with the H-atom bonded either to C (HCCl2+) or to Cl (CClH2+). The isomer CClH2+, of a higher ionization energy than HCCl2+, was found to be responsible for most of the charge transfer product (formation of the ground and excited states of CClH+). Chemical reactions and charge transfer processes in the system CHCl2+ + D2 were investigated in crossed beam scattering experiments. Experimental data were complemented by theoretical calculations of the energetics of the species involved and by calculations of stationary points on the dication potential energy surfaces. The main reaction products were the cations CHCl+, CHDCl+, and CCl+. Integral cross sections for formation of these species were determined over the collision energy range 0.4-2.5 eV (center-of-mass, C.M.). Two isomers of the reactant dication were identified, with the H-atom bonded either to C (HCCl2+) or to Cl (CClH2+). The isomer CClH2+, of a higher ionization energy than HCCl2+, was found to be responsible for most of the charge transfer product (formation of the ground and excited states of CClH+). (en)
Title	Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: IV. Proton Transfer and Reactions of Dication Isomers in the CHCl2+ +D2 System. Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: IV. Proton Transfer and Reactions of Dication Isomers in the CHCl2+ +D2 System. (en)
skos:prefLabel	Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: IV. Proton Transfer and Reactions of Dication Isomers in the CHCl2+ +D2 System. Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: IV. Proton Transfer and Reactions of Dication Isomers in the CHCl2+ +D2 System. (en)
skos:notation	RIV/61388955:_____/03:54030164!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	7347;7354
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/00/0632), P(KJB4040302), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Hrušák, Jan Žabka, Ján Herman, Zdeněk Roithová, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	604723
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030164
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	dynamics of chemical; molecular dications; proton transfer (en)
http://linked.open.../riv/klicoveSlovo	proton transfer dynamics of chemical molecular dications
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[B8ADCB712F3A]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry. A
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Chemistry of ions in the gaseous phase and ion-surface collisions Reactions of Molecular Dications HCX++ (X = F, Cl, Br, OH, SH, NH2): Theoretical and Experimental Investigation
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	107
http://linked.open...iv/tvurceVysledku	Žabka, Ján Herman, Zdeněk Roithová, Jana Thissen, R. Hrušák, Jan
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	1089-5639
number of pages	8 (xsd:int)

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