About: Internal energy effects in the reactivity of CO2 2+ doubly charged molecular ions with CO2 and CO.

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About: Internal energy effects in the reactivity of CO2 2+ doubly charged molecular ions with CO2 and CO. Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reactivity of the dication CO22+ in dependence on its internal energy was studied in collisions with CO2 and CO. The dication was obtained by photoionization of the CO2 molecule by synchrotron radiation and the guided beam apparatus CERISES was used in these studies. Spontaneous dissociation of CO22+ to CO+ and O+ was observed without any target gas in the reaction cell. With CO2 or CO as a target gas, fragment ion CO+ and O+ were formed as products of dissociative charge transfer, while the contribution of collision induced dissociation of the reactant CO22+ to their formation was found negligible. The CO+ yield showed a considerable dependence on the internal energy of the reactant dication CO22+: the branching ratio CO+/O+ increased gradually with photon energy between 38.5 and 40 eV. We interpret this observation as being due to the increase in the accessible. Reactivity of the dication CO22+ in dependence on its internal energy was studied in collisions with CO2 and CO. The dication was obtained by photoionization of the CO2 molecule by synchrotron radiation and the guided beam apparatus CERISES was used in these studies. Spontaneous dissociation of CO22+ to CO+ and O+ was observed without any target gas in the reaction cell. With CO2 or CO as a target gas, fragment ion CO+ and O+ were formed as products of dissociative charge transfer, while the contribution of collision induced dissociation of the reactant CO22+ to their formation was found negligible. The CO+ yield showed a considerable dependence on the internal energy of the reactant dication CO22+: the branching ratio CO+/O+ increased gradually with photon energy between 38.5 and 40 eV. We interpret this observation as being due to the increase in the accessible. (en)
Title	Internal energy effects in the reactivity of CO2 2+ doubly charged molecular ions with CO2 and CO. Internal energy effects in the reactivity of CO2 2+ doubly charged molecular ions with CO2 and CO. (en)
skos:prefLabel	Internal energy effects in the reactivity of CO2 2+ doubly charged molecular ions with CO2 and CO. Internal energy effects in the reactivity of CO2 2+ doubly charged molecular ions with CO2 and CO. (en)
skos:notation	RIV/61388955:_____/03:54030159!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	507;516
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/00/0632), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Žabka, Ján Herman, Zdeněk Roithová, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	610938
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030159
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	dication; ion-molecule reactions; photoionization (en)
http://linked.open.../riv/klicoveSlovo	dication ion-molecule reactions photoionization
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[555D89ACA634]
http://linked.open...i/riv/nazevZdroje	International Journal of Mass Spectrometry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Chemistry of ions in the gaseous phase and ion-surface collisions
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	228
http://linked.open...iv/tvurceVysledku	Žabka, Ján Herman, Zdeněk Roithová, Jana Dutuit, O. Franceschi, P. Thissen, R.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	1387-3806
number of pages	10 (xsd:int)

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