About: Submillimeter-wave Spectroscopy of HCN in Excited Vibrational States.

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About: Submillimeter-wave Spectroscopy of HCN in Excited Vibrational States. Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Measurements of the rotational spectrum of HCN in excited vibrational states have been extended to higher J values. The transitions reach J = 8 üř 7 around 710 GHz for most vibrational states studied in this investigation and J = 22 üř 21 near 2 THz for the (020) vibrational state. Using a pure sample of gaseous HCN at íŔ350 K, selected states up to one quantum in the C-H stretching vibration at 3311.5 cm-1 have been investigated. Even transitions having two quanta in the C-H stretch could be studied employing a glow discharge in a gas mixture of CH4 and N2. Molecular constants in 13 vibrational states have been obtained, several of which have been studied for the first time by rotational spectroscopy. The vibrational temperature in the discharge system is found to be about 1500 K for the stretching vibrational modes and about 600 K for the bending states. Measurements of the rotational spectrum of HCN in excited vibrational states have been extended to higher J values. The transitions reach J = 8 üř 7 around 710 GHz for most vibrational states studied in this investigation and J = 22 üř 21 near 2 THz for the (020) vibrational state. Using a pure sample of gaseous HCN at íŔ350 K, selected states up to one quantum in the C-H stretching vibration at 3311.5 cm-1 have been investigated. Even transitions having two quanta in the C-H stretch could be studied employing a glow discharge in a gas mixture of CH4 and N2. Molecular constants in 13 vibrational states have been obtained, several of which have been studied for the first time by rotational spectroscopy. The vibrational temperature in the discharge system is found to be about 1500 K for the stretching vibrational modes and about 600 K for the bending states. (en)
Title	Submillimeter-wave Spectroscopy of HCN in Excited Vibrational States. Submillimeter-wave Spectroscopy of HCN in Excited Vibrational States. (en)
skos:prefLabel	Submillimeter-wave Spectroscopy of HCN in Excited Vibrational States. Submillimeter-wave Spectroscopy of HCN in Excited Vibrational States. (en)
skos:notation	RIV/61388955:_____/03:54030124!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	223;233
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(ME 445), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Zelinger, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	629668
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030124
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	rotational spectroscopy; glow discharge; HCN (en)
http://linked.open.../riv/klicoveSlovo	rotational spectroscopy HCN glow discharge
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[F0C67B854F75]
http://linked.open...i/riv/nazevZdroje	Journal of Molecular Spectroscopy
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/ME%20445
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	220
http://linked.open...iv/tvurceVysledku	Zelinger, Zdeněk Amano, T. Müller, H. S. P. Ahrens, V. Lewen, F. Brünken, S. Winnewiser, G.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0022-2852
number of pages	11 (xsd:int)

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