About: Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: Part V. An Experimental and Theoretical Study of Reactions between CHCl2+ and Ar, Kr and Xe.

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About: Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: Part V. An Experimental and Theoretical Study of Reactions between CHCl2+ and Ar, Kr and Xe. Goto Sponge NotDistinct Permalink

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Description	Non-dissociative charge transfer processes between the dication CHCl2+ and noble gases Ar, Kr, and Xe were investigated in crossed-beam scattering experiments. Translational energy distributions of the product CHCl+ revealed that two isomers of CHCl2+ of different energetics were taking part in these processes. In reactions with Ar, the charge transfer products are formed mainly in reactions of the CCl-H2+ isomer in the ground (iS0) and first excited (iT1) state, leading to the ground (iD0) and first excited (iD1) state of the cation CCl-H+. Part of the vibrationally excited product (iD0) may dissociate further to give CCl+ + H. The main reaction in the system with Ar is, however, an impulsive proton transfer process of the other isomer, H-CCl2+(S0) leading to CCl+ + ArH+. The prevailing reaction with Kr is charge transfer leading to dication-cations transition CClH2+(CClH+(iD0), CClH2+(iS0)&61614; CClH+(iD1), and CClH2+(iT0)61614;CClH+(iD1) and Kr+ in both spin-orbit states. Non-dissociative charge transfer processes between the dication CHCl2+ and noble gases Ar, Kr, and Xe were investigated in crossed-beam scattering experiments. Translational energy distributions of the product CHCl+ revealed that two isomers of CHCl2+ of different energetics were taking part in these processes. In reactions with Ar, the charge transfer products are formed mainly in reactions of the CCl-H2+ isomer in the ground (iS0) and first excited (iT1) state, leading to the ground (iD0) and first excited (iD1) state of the cation CCl-H+. Part of the vibrationally excited product (iD0) may dissociate further to give CCl+ + H. The main reaction in the system with Ar is, however, an impulsive proton transfer process of the other isomer, H-CCl2+(S0) leading to CCl+ + ArH+. The prevailing reaction with Kr is charge transfer leading to dication-cations transition CClH2+(CClH+(iD0), CClH2+(iS0)&61614; CClH+(iD1), and CClH2+(iT0)61614;CClH+(iD1) and Kr+ in both spin-orbit states. (en)
Title	Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: Part V. An Experimental and Theoretical Study of Reactions between CHCl2+ and Ar, Kr and Xe. Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: Part V. An Experimental and Theoretical Study of Reactions between CHCl2+ and Ar, Kr and Xe. (en)
skos:prefLabel	Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: Part V. An Experimental and Theoretical Study of Reactions between CHCl2+ and Ar, Kr and Xe. Dynamics of Chemical and Charge Transfer Reactions of Molecular Dications: Part V. An Experimental and Theoretical Study of Reactions between CHCl2+ and Ar, Kr and Xe. (en)
skos:notation	RIV/61388955:_____/03:54030096!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	2988;2995
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/00/0632), P(KJB4040302), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Žabka, Ján Herman, Zdeněk Roithová, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	604724
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030096
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	charge-transfer; experimental and theoretical study; molecular dications (en)
http://linked.open.../riv/klicoveSlovo	charge-transfer experimental and theoretical study molecular dications
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[8FD4DFC67370]
http://linked.open...i/riv/nazevZdroje	Physical Chemistry Chemical Physics
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Chemistry of ions in the gaseous phase and ion-surface collisions Reactions of Molecular Dications HCX++ (X = F, Cl, Br, OH, SH, NH2): Theoretical and Experimental Investigation
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	5
http://linked.open...iv/tvurceVysledku	Žabka, Ján Herman, Zdeněk Roithová, Jana Thissen, R.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	1463-9076
number of pages	8 (xsd:int)

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