About: Electrochemical Detection of HostůGuest Interactions of Dicarboximide Pesticides with Cyclodextrins.

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About: Electrochemical Detection of HostůGuest Interactions of Dicarboximide Pesticides with Cyclodextrins. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Electrochemical methods sensitively detect the formation of hostůguest complexes of cyclodextrins and three redoxůactive pesticides: vinclozoline (3ů(3,5ůdichlorophenyl)ů5ůmethylů5ůvinylů1,3ůoxazolidineů2,4ůdione), iprodione (3ů(3,5ůdichlorophenyl)ůNů(1ůmethylethyl)ů2,4ůdioxoů1ůimidazolidinecarboxamide), and procymidone (3ů(3,5ůdichloroůphenyl)ů1,5ůdimethylů3ůazabicyclo[3.1.0]hexaneů2,4ůdione). The protecting environment of CD cavity allows a fourůelectron heterogeneous reaction leading to a preferential cleavage of the CůCl bonds and conservation of the heterocycle structure for further second electron transfer step. This interpretation is supported by numerical simulation of the voltammetric curves and by quantumůchemical calculations of the LUMO changes of vinclozoline. Electrochemical detection of these hostůguest interactions is by far superior to the spectral methods. Electrochemical methods sensitively detect the formation of hostůguest complexes of cyclodextrins and three redoxůactive pesticides: vinclozoline (3ů(3,5ůdichlorophenyl)ů5ůmethylů5ůvinylů1,3ůoxazolidineů2,4ůdione), iprodione (3ů(3,5ůdichlorophenyl)ůNů(1ůmethylethyl)ů2,4ůdioxoů1ůimidazolidinecarboxamide), and procymidone (3ů(3,5ůdichloroůphenyl)ů1,5ůdimethylů3ůazabicyclo[3.1.0]hexaneů2,4ůdione). The protecting environment of CD cavity allows a fourůelectron heterogeneous reaction leading to a preferential cleavage of the CůCl bonds and conservation of the heterocycle structure for further second electron transfer step. This interpretation is supported by numerical simulation of the voltammetric curves and by quantumůchemical calculations of the LUMO changes of vinclozoline. Electrochemical detection of these hostůguest interactions is by far superior to the spectral methods. (en)
Title	Electrochemical Detection of HostůGuest Interactions of Dicarboximide Pesticides with Cyclodextrins. Electrochemical Detection of HostůGuest Interactions of Dicarboximide Pesticides with Cyclodextrins. (en)
skos:prefLabel	Electrochemical Detection of HostůGuest Interactions of Dicarboximide Pesticides with Cyclodextrins. Electrochemical Detection of HostůGuest Interactions of Dicarboximide Pesticides with Cyclodextrins. (en)
skos:notation	RIV/61388955:_____/03:54030035!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	373;380
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC D15.10), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Pospíšil, Lubomír Hromadová, Magdaléna Záliš, Stanislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	605616
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030035
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	electrochemistry; cyclodextrin; iprodione (en)
http://linked.open.../riv/klicoveSlovo	cyclodextrin electrochemistry iprodione
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[A9ECDC2AF1DA]
http://linked.open...i/riv/nazevZdroje	Journal of Inclusion Phenomena and Macrocyclic Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20D15.10
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	44
http://linked.open...iv/tvurceVysledku	Pospíšil, Lubomír Záliš, Stanislav Hromadová, Magdalena Fanneli, N.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0923-0750
number of pages	8 (xsd:int)

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