About: Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions.

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About: Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Thermodynamic analysis of the polarised interface between two immiscible electrolyte solutions (ITIES) was outlined, which accounts for the adsorption of phosphatidylcholine (PC) both as a zwitterion and a cation formed by the aqueous cation association with the zwitterionic PC form, as well as for the aqueous cation transfer facilitated by PC leading to its depletion from the interface. Electrocapillary equation was derived clarifying the physical significance of the surface charge density; the differential capacity and the PC surface excess concentration. The potential dependence of the interfacial tension calculated using the Damaskins adsorption model of a compound adsorbed in two different forms was found to agree well with that measured for the polarised water \|1,2-dichloroethane interface in the presence of DL-alpha-dipalmitoylphosphatidylcholine. Experimentally observed effect of the nature of the aqueous cation on the interfacial tension was ascribed to the difference. Thermodynamic analysis of the polarised interface between two immiscible electrolyte solutions (ITIES) was outlined, which accounts for the adsorption of phosphatidylcholine (PC) both as a zwitterion and a cation formed by the aqueous cation association with the zwitterionic PC form, as well as for the aqueous cation transfer facilitated by PC leading to its depletion from the interface. Electrocapillary equation was derived clarifying the physical significance of the surface charge density; the differential capacity and the PC surface excess concentration. The potential dependence of the interfacial tension calculated using the Damaskins adsorption model of a compound adsorbed in two different forms was found to agree well with that measured for the polarised water \|1,2-dichloroethane interface in the presence of DL-alpha-dipalmitoylphosphatidylcholine. Experimentally observed effect of the nature of the aqueous cation on the interfacial tension was ascribed to the difference. (en)
Title	Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions. Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions. (en)
skos:prefLabel	Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions. Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions. (en)
skos:notation	RIV/61388955:_____/03:54030001!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	98;103
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/01/0946), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Samec, Zdeněk Trojánek, Antonín
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	630929
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030001
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ITIES; phosphatidylcholine; adsorption (en)
http://linked.open.../riv/klicoveSlovo	adsorption phosphatidylcholine ITIES
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[926F8A2FF1CE]
http://linked.open...i/riv/nazevZdroje	Electrochemistry Communications
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Quasielastic laser scattering on phospholipid monolayers
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	5
http://linked.open...iv/tvurceVysledku	Girault, H. H. Samec, Zdeněk Trojánek, Antonín
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	1388-2481
number of pages	6 (xsd:int)

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