About: Oxidative Dehydrogenation and Ammoxidation of Ethane and Propane over Pentasil Ring Co-zeolites.     Goto   Sponge   NotDistinct   Permalink

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  • The activity of Co-zeolites with MFI, BEA, FER, MOR topologies was studied in ethane and propane oxidative dehydrogenation and ammoxidation in a through-flow arrangement and temperature range 350-500degreesC. The products of oxidative dehydrogenation of paraffins were corresponding olefins, CO and CO2, in the propane reaction only a small part was cracked to ethylene and methane. Besides CO and CO2, the ammoxidation of ethane yielded ethylene and acetonitrile, and of propane brought propylene and acetonitrile too. Presence of ammonia increased substantially the paraffin conversion as well as selectivity and yield of the sum of olefin and nitrile for CoH-BEA and CoH-MFI zeolites, while with CoNa-zeolites the paraffin conversion and selectivity were similar.
  • The activity of Co-zeolites with MFI, BEA, FER, MOR topologies was studied in ethane and propane oxidative dehydrogenation and ammoxidation in a through-flow arrangement and temperature range 350-500degreesC. The products of oxidative dehydrogenation of paraffins were corresponding olefins, CO and CO2, in the propane reaction only a small part was cracked to ethylene and methane. Besides CO and CO2, the ammoxidation of ethane yielded ethylene and acetonitrile, and of propane brought propylene and acetonitrile too. Presence of ammonia increased substantially the paraffin conversion as well as selectivity and yield of the sum of olefin and nitrile for CoH-BEA and CoH-MFI zeolites, while with CoNa-zeolites the paraffin conversion and selectivity were similar. (en)
Title
  • Oxidative Dehydrogenation and Ammoxidation of Ethane and Propane over Pentasil Ring Co-zeolites.
  • Oxidative Dehydrogenation and Ammoxidation of Ethane and Propane over Pentasil Ring Co-zeolites. (en)
skos:prefLabel
  • Oxidative Dehydrogenation and Ammoxidation of Ethane and Propane over Pentasil Ring Co-zeolites.
  • Oxidative Dehydrogenation and Ammoxidation of Ethane and Propane over Pentasil Ring Co-zeolites. (en)
skos:notation
  • RIV/61388955:_____/02:54020239!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany
  • 181;191
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/00/0640), P(GA203/99/D073), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • N/A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 657643
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/02:54020239
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • ethane; propane; ammoxidation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [277679399ADD]
http://linked.open...i/riv/nazevZdroje
  • Applied Catalysis. A
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 235
http://linked.open...iv/tvurceVysledku
  • Bulánek, R.
  • Wichterlová, Blanka
  • Novoveská, K.
http://linked.open...n/vavai/riv/zamer
issn
  • 0926-860X
number of pages
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