About: Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity.

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About: Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity. Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Ketoximes and their metal chelate complexes are both active as catalysts in hydrolysis of esters. Electroreduction of five azinylmethylketoximes I-V and their Ni(II), Cu(II) and Zn(II) complexes was investigated polarographically and correlated with acidity of hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenylacetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed. Ketoximes and their metal chelate complexes are both active as catalysts in hydrolysis of esters. Electroreduction of five azinylmethylketoximes I-V and their Ni(II), Cu(II) and Zn(II) complexes was investigated polarographically and correlated with acidity of hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenylacetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed. (en)
Title	Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity. Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity. (en)
skos:prefLabel	Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity. Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity. (en)
skos:notation	RIV/61388955:_____/02:54020201!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	142;146
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/01/1093), Z(AV0Z4040901)
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Ludvík, Jiří
http://linked.open.../riv/druhVysledku	C - Kapitola v knize
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	644816
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/02:54020201
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ketoximes; chelates; electroreduction (en)
http://linked.open.../riv/klicoveSlovo	chelates ketoximes electroreduction
http://linked.open...ontrolniKodProRIV	[9F2ECF8621F9]
http://linked.open...i/riv/mistoVydani	Pennington
http://linked.open...vEdiceCisloSvazku	(1)
http://linked.open...i/riv/nazevZdroje	Organic Electrochemistry.
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	The effect of electron distribution on the oxime reactivity towards esters
http://linked.open...UplatneniVysledku	2002
http://linked.open...iv/tvurceVysledku	Cibulka, R. Ludvík, Jiří
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
number of pages	5 (xsd:int)
http://purl.org/ne...btex#hasPublisher	ECS

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