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rdf:type
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Description
| - The structure and gas-phase ion chemistry of 2-hydroxyoxol-2-ene cation-radical(1) have been studied by experiment using accurate mass measurements, isotope labeling, metastable-ion and collisionally-activated dissociation mass spectra and by RRKM calculations on G2(MP2)potential energy surface. Namely, elimination of CO molecule from metastable 1 has been addressed. Molecular rearrangement involving multiple consecutive hydrogen migrations explained unusual deuterium kinetic isotope effects on the CO elimination.
- The structure and gas-phase ion chemistry of 2-hydroxyoxol-2-ene cation-radical(1) have been studied by experiment using accurate mass measurements, isotope labeling, metastable-ion and collisionally-activated dissociation mass spectra and by RRKM calculations on G2(MP2)potential energy surface. Namely, elimination of CO molecule from metastable 1 has been addressed. Molecular rearrangement involving multiple consecutive hydrogen migrations explained unusual deuterium kinetic isotope effects on the CO elimination. (en)
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Title
| - Lactone Enol Cation-Radicals. Gas-Phase Generation, Structure, Energetics, and Reactivity of the Ionized Enol of Butane-4-Lactone.
- Lactone Enol Cation-Radicals. Gas-Phase Generation, Structure, Energetics, and Reactivity of the Ionized Enol of Butane-4-Lactone. (en)
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skos:prefLabel
| - Lactone Enol Cation-Radicals. Gas-Phase Generation, Structure, Energetics, and Reactivity of the Ionized Enol of Butane-4-Lactone.
- Lactone Enol Cation-Radicals. Gas-Phase Generation, Structure, Energetics, and Reactivity of the Ionized Enol of Butane-4-Lactone. (en)
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skos:notation
| - RIV/61388955:_____/02:54020039!RIV/2003/AV0/A54003/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/00/0632), Z(AV0Z4040901)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/02:54020039
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - lactone enol ions; - dissociation mechanisms; - isotope effects (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Mass Spectrometry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Polášek, Miroslav
- Tureček, F.
- Sadílek, M.
- Vivekananda, S.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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