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  • The existence of binuclear oxo-iron clusters in Fe/ZSM-5, which was postulated on the basis of FTIR and CO/H2 TPR experiments, was unambiguously confirmed by EXAFS. By comparison with data of Fe model-complexes available in the literature, it is proposed that the Fe species adopt a structure closely resembling the 'diamond core' of the methane monooxygenase enzyme (Fe(.mu.-OH)2Fe).
  • The existence of binuclear oxo-iron clusters in Fe/ZSM-5, which was postulated on the basis of FTIR and CO/H2 TPR experiments, was unambiguously confirmed by EXAFS. By comparison with data of Fe model-complexes available in the literature, it is proposed that the Fe species adopt a structure closely resembling the 'diamond core' of the methane monooxygenase enzyme (Fe(.mu.-OH)2Fe). (en)
Title
  • Exafs Study of Fe/ZSM-5 Prepared by Chemical Vapour Deposition and Co/FER, MOR, MFI Prepared by Ion Exchange.
  • Exafs Study of Fe/ZSM-5 Prepared by Chemical Vapour Deposition and Co/FER, MOR, MFI Prepared by Ion Exchange. (en)
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  • Exafs Study of Fe/ZSM-5 Prepared by Chemical Vapour Deposition and Co/FER, MOR, MFI Prepared by Ion Exchange.
  • Exafs Study of Fe/ZSM-5 Prepared by Chemical Vapour Deposition and Co/FER, MOR, MFI Prepared by Ion Exchange. (en)
skos:notation
  • RIV/61388955:_____/01:54010232!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany
  • 85;94
http://linked.open...avai/riv/aktivita
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  • P(OC D15.20), Z(AV0Z4040901)
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  • 679844
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  • RIV/61388955:_____/01:54010232
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  • Fe/ZSM-5; - FTIR and CO/H2; - Fe model-complexes (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [11D560DD53EC]
http://linked.open...v/mistoKonaniAkce
  • Praha-Průhonice [CZ]
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  • Dordrecht
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  • Proceedings of the NATO Advanced Research Workshop on Catalysis by Unique Metal Ion Structures in Solid Matrices.
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  • Wichterlová, Blanka
  • Drozdová, L.
  • Prins, R.
  • Kogelbauer, A.
  • Marturano, P.
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Kluwer
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