About: Heterocubane-Cluster-Compounds (Net 4 ){Y=M[(.mu. 3 -S)Re(CO) 3 ] 3 (.mu. 3 -E)} (M=W or Mo, Y=O or S, E=S or Se): Structures, Spectroscopy, and Electrochemistry.     Goto   Sponge   NotDistinct   Permalink

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Description
  • Aus den thiometallen Re(CO)5(O3SCF3) and Li2E (E=S oder Se) verbindungen erhalten und strukturell charakterisiert. Die heterokuban-anionen besitzen einerseits elektronenreiche zentren(rhenium(I), sulfid) sowie andererseits molybdän(VI) oder wolfram(VI) atome als akzeptoren, dementsprechend werden absorptionsspektroskopisch metal-ligand-charge-transfer-übergänge und cyclovoltammetrisch. Zentren in den clustern gibt es keine hinweise auf signifikante matell-metall-charge-transfer-wechselwirkungen.
  • Compounds formed by reaction of thiometallates with Re(CO)5(O3SCF) and Li2Se were structurally characterized. Heterokubane anions contain electro-rich centers such as rhenium(I) or sulfide whereas molybdenum(VI) or tungsten(VI) act as acceptor sites. Absorption spectra show long-wavelength metal-to-ligand charge transfer transi-tions, and cyclic voltammetry reveals a quasi-reversible reduction of the clusters. No evidence for significant metal-to-metal charge transfer interaction was found. (en)
Title
  • Heterocubane-Cluster-Compounds (Net 4 ){Y=M[(.mu. 3 -S)Re(CO) 3 ] 3 (.mu. 3 -E)} (M=W or Mo, Y=O or S, E=S or Se): Structures, Spectroscopy, and Electrochemistry. (en)
  • Heterokuban-Cluster-Verbindungen (NEt 4 ){Y=M[(.mu. 3 -S)Re(CO) 3 ] 3 (.mu. 3 -E)} (M=W oder Mo, Y=O oder S, E=S oder Se): Strukturen, Spektroskopie und Elektrochemie.
skos:prefLabel
  • Heterocubane-Cluster-Compounds (Net 4 ){Y=M[(.mu. 3 -S)Re(CO) 3 ] 3 (.mu. 3 -E)} (M=W or Mo, Y=O or S, E=S or Se): Structures, Spectroscopy, and Electrochemistry. (en)
  • Heterokuban-Cluster-Verbindungen (NEt 4 ){Y=M[(.mu. 3 -S)Re(CO) 3 ] 3 (.mu. 3 -E)} (M=W oder Mo, Y=O oder S, E=S oder Se): Strukturen, Spektroskopie und Elektrochemie.
skos:notation
  • RIV/61388955:_____/01:54010184!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany
  • 2430;2444
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ME 439), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • N/A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 681589
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/01:54010184
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cluster compound; - crystal strukture; - thiometallate (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [6B8E9DA4F2A8]
http://linked.open...i/riv/nazevZdroje
  • Zeitschrift für Anorganische und Allgemeine Chemie
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 627
http://linked.open...iv/tvurceVysledku
  • Fiedler, Jan
  • Kaim, W.
  • Hornung, F. M.
  • Wanner, M.
  • Klinkhammer, K. W.
http://linked.open...n/vavai/riv/zamer
issn
  • 0044-2313
number of pages
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