About: Coupling of Electron Transfer and Bond Dissociation Processes in Dinuclear Complexes with Rhodium and Iridium Reaction Centers Bridged by 2,2'-Bipyrimidine.

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About: Coupling of Electron Transfer and Bond Dissociation Processes in Dinuclear Complexes with Rhodium and Iridium Reaction Centers Bridged by 2,2'-Bipyrimidine. Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Cyclic voltammetry and spectroscopy (NMR, EPR, UV-Vis) was used to analyze reduction of the complexes [{M(C5Me5)}2(bpym)](PF6)2 with up to five electrons. In acetonitrile at room temperature, the dirhodium compound displays two sequential chloride-dissociative two-electroncathodic steps. At -15.mult.C in DMF, the diiridium compound was found to be sufficiently inert towards dissociation; it is then reversibly reduced to an EPR-detactable radical cation [{IrCl(C5Me5)}2(bpym)]+. Cyclic voltammetry and spectroscopy (NMR, EPR, UV-Vis) was used to analyze reduction of the complexes [{M(C5Me5)}2(bpym)](PF6)2 with up to five electrons. In acetonitrile at room temperature, the dirhodium compound displays two sequential chloride-dissociative two-electroncathodic steps. At -15.mult.C in DMF, the diiridium compound was found to be sufficiently inert towards dissociation; it is then reversibly reduced to an EPR-detactable radical cation [{IrCl(C5Me5)}2(bpym)]+. (en)
Title	Coupling of Electron Transfer and Bond Dissociation Processes in Dinuclear Complexes with Rhodium and Iridium Reaction Centers Bridged by 2,2'-Bipyrimidine. Coupling of Electron Transfer and Bond Dissociation Processes in Dinuclear Complexes with Rhodium and Iridium Reaction Centers Bridged by 2,2'-Bipyrimidine. (en)
skos:prefLabel	Coupling of Electron Transfer and Bond Dissociation Processes in Dinuclear Complexes with Rhodium and Iridium Reaction Centers Bridged by 2,2'-Bipyrimidine. Coupling of Electron Transfer and Bond Dissociation Processes in Dinuclear Complexes with Rhodium and Iridium Reaction Centers Bridged by 2,2'-Bipyrimidine. (en)
skos:notation	RIV/61388955:_____/01:54010120!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	291;306
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC D15.10), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Fiedler, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	676534
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/01:54010120
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	EPR spectroscopy; - iridium complexes; - rhodium complexes (en)
http://linked.open.../riv/klicoveSlovo	EPR spectroscopy - iridium complexes - rhodium complexes
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[B02275F39572]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20D15.10
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	66
http://linked.open...iv/tvurceVysledku	Fiedler, Jan Kaim, W. Sieger, M. Klein, A. Greulich, S. Reinhardt, R.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0010-0765
number of pages	16 (xsd:int)

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