About: Ruthenium-Aminoallenylidene Complexes from Butatrienylidene Intermediates via an Aza-Cope Rearrangement: Synthetic, Spectroscopic, Electrochemical, Spectroelectrochemical and Computational Studies.

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About: Ruthenium-Aminoallenylidene Complexes from Butatrienylidene Intermediates via an Aza-Cope Rearrangement: Synthetic, Spectroscopic, Electrochemical, Spectroelectrochemical and Computational Studies. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Aminoallenylidene ruthenium complexes trans-[Cl(L2)2RuCCC(NR2)CH2R'] + EF6-(4a-f, E=P,Sb, L2=chelating diphosphine) were synthetised and characterized by various spectroscopic techniques including NMR-, IR-, and UV/Vis-spectroscopy, cyclic voltammetry. DFT calculations have been performed on model complexes trans-[Cl(L2)2Ru=C=C=C=CH2] + and trans-[Cl(L2)2RuC3{N(CH3)2}CH3] +. The calculations further indicate primarily metal based oxidation and ligand based reduction. Aminoallenylidene ruthenium complexes trans-[Cl(L2)2RuCCC(NR2)CH2R'] + EF6-(4a-f, E=P,Sb, L2=chelating diphosphine) were synthetised and characterized by various spectroscopic techniques including NMR-, IR-, and UV/Vis-spectroscopy, cyclic voltammetry. DFT calculations have been performed on model complexes trans-[Cl(L2)2Ru=C=C=C=CH2] + and trans-[Cl(L2)2RuC3{N(CH3)2}CH3] +. The calculations further indicate primarily metal based oxidation and ligand based reduction. (en)
Title	Ruthenium-Aminoallenylidene Complexes from Butatrienylidene Intermediates via an Aza-Cope Rearrangement: Synthetic, Spectroscopic, Electrochemical, Spectroelectrochemical and Computational Studies. Ruthenium-Aminoallenylidene Complexes from Butatrienylidene Intermediates via an Aza-Cope Rearrangement: Synthetic, Spectroscopic, Electrochemical, Spectroelectrochemical and Computational Studies. (en)
skos:prefLabel	Ruthenium-Aminoallenylidene Complexes from Butatrienylidene Intermediates via an Aza-Cope Rearrangement: Synthetic, Spectroscopic, Electrochemical, Spectroelectrochemical and Computational Studies. Ruthenium-Aminoallenylidene Complexes from Butatrienylidene Intermediates via an Aza-Cope Rearrangement: Synthetic, Spectroscopic, Electrochemical, Spectroelectrochemical and Computational Studies. (en)
skos:notation	RIV/61388955:_____/01:54010059!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	1317;1333
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC D14.20), P(OC D15.10), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	7
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Záliš, Stanislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	695165
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/01:54010059
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ruthenium complexes; - spectroelectrochemistry; - DFT calculations (en)
http://linked.open.../riv/klicoveSlovo	- spectroelectrochemistry - DFT calculations ruthenium complexes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[8ABCFD3058F9]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20D14.20 http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20D15.10
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	20
http://linked.open...iv/tvurceVysledku	Záliš, Stanislav Winter, R. F. Klinkhammer, K. W.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0276-7333
number of pages	17 (xsd:int)

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