About: Reduction of Peroxodisulfate on Gold(111) Covered by Surface Oxides: Inhibition and Coupling between Two Oxide Reduction Processes.     Goto   Sponge   NotDistinct   Permalink

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  • Cyclic voltammetry and potentiostatic current transient measurements with the rotating disc electrode are used to study the reduction of peroxodisulfate(PDS) on Au(111) covered by surface oxides. A strong inhibition is observed. Evidence is provided that the inhibition is related to the coverage of Au(111) by the more stable oxide. The difference between the kinetics of the reduction of the two main oxide species on Au(111) is ascribed to a coupling between the two processes.
  • Cyclic voltammetry and potentiostatic current transient measurements with the rotating disc electrode are used to study the reduction of peroxodisulfate(PDS) on Au(111) covered by surface oxides. A strong inhibition is observed. Evidence is provided that the inhibition is related to the coverage of Au(111) by the more stable oxide. The difference between the kinetics of the reduction of the two main oxide species on Au(111) is ascribed to a coupling between the two processes. (en)
Title
  • Reduction of Peroxodisulfate on Gold(111) Covered by Surface Oxides: Inhibition and Coupling between Two Oxide Reduction Processes.
  • Reduction of Peroxodisulfate on Gold(111) Covered by Surface Oxides: Inhibition and Coupling between Two Oxide Reduction Processes. (en)
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  • Reduction of Peroxodisulfate on Gold(111) Covered by Surface Oxides: Inhibition and Coupling between Two Oxide Reduction Processes.
  • Reduction of Peroxodisulfate on Gold(111) Covered by Surface Oxides: Inhibition and Coupling between Two Oxide Reduction Processes. (en)
skos:notation
  • RIV/61388955:_____/01:54010052!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany
  • 129;135
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  • Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • 1
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  • 694225
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  • RIV/61388955:_____/01:54010052
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  • reaction mechanism; - peroxodisulfate reduction; - Au(111) electrode (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [AACDAF619EE7]
http://linked.open...i/riv/nazevZdroje
  • Journal of Electroanalytical Chemistry
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http://linked.open...v/svazekPeriodika
  • 499
http://linked.open...iv/tvurceVysledku
  • Samec, Zdeněk
  • Doblhofer, K.
  • Krischer, K.
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-0728
number of pages
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