About: Synthesis of C 2 -Symmetrical [1,1'-Binaphthalene]-2,2'-Diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis.

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About: Synthesis of C 2 -Symmetrical [1,1'-Binaphthalene]-2,2'-Diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reductive amination of 2-hydroxybenzaldehyde using a combination of NaBH4 and (R)-[1,1'-binaphthalene]-2,2'-diamine, served as the key step in the synthesis of the potentially tetradentate ligands (R)-N,N'-bis(2-hydroxybenzyl)[1,1'-binaphthalene]-2,2'-diamine and (R)-N,N'-bis(2-hydroxybenzyl)-N,N'-dimethyl[1,1'-binaphthalene]-2,2'-diamine. CD spectra of the new binaphthyl derivatives are presented. Reductive amination of 2-hydroxybenzaldehyde using a combination of NaBH4 and (R)-[1,1'-binaphthalene]-2,2'-diamine, served as the key step in the synthesis of the potentially tetradentate ligands (R)-N,N'-bis(2-hydroxybenzyl)[1,1'-binaphthalene]-2,2'-diamine and (R)-N,N'-bis(2-hydroxybenzyl)-N,N'-dimethyl[1,1'-binaphthalene]-2,2'-diamine. CD spectra of the new binaphthyl derivatives are presented. (en)
Title	Synthesis of C 2 -Symmetrical [1,1'-Binaphthalene]-2,2'-Diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis. Synthesis of C 2 -Symmetrical [1,1'-Binaphthalene]-2,2'-Diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis. (en)
skos:prefLabel	Synthesis of C 2 -Symmetrical [1,1'-Binaphthalene]-2,2'-Diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis. Synthesis of C 2 -Symmetrical [1,1'-Binaphthalene]-2,2'-Diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis. (en)
skos:notation	RIV/61388955:_____/00:54010187!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	539;548
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/98/1185), Z(AV0Z4040901), Z(AV0Z4055905), Z(MSM 113100001)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Kubišta, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	728688
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/00:54010187
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	biaryls; - binaphthyls; - amine reductive alkylation (en)
http://linked.open.../riv/klicoveSlovo	- amine reductive alkylation - binaphthyls biaryls
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[6ED6D9BDA300]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Binaphtyl ligands with bulky and chelating groups in 2,22' - positions and their application for asymmetric synthesis
http://linked.open...UplatneniVysledku	2000
http://linked.open...v/svazekPeriodika	65
http://linked.open...iv/tvurceVysledku	Kočovský, P. Maloň, Petr Kubišta, Jiří Vyskočil, Š. Meca, L.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20113100001 Chemical principles of selected biological phenomena in medicine and ecology
issn	0010-0765
number of pages	10 (xsd:int)

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