About: Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 .

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About: Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 . Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The complexes [(DMA)Cu(PPh 3 ) 2 ](BF 4 )(1), [(DMA)Ru(bpy) 2 ](PF 6 ) 2 (2) and (DMA)WOCl 3 (3) with 1,3-dimethylalloxazine (DMA) were obtained as O 4 -N 5 cheladet species, as evident from an X-ray crystal structure analysis for 3and from spectroscopy (NMR, IR and UV/vis spectroelectrochemistry).DFT and ab initio methodology is used to illustrate the correspondence in spin distribution between the anion radical p systems of alloxazine and isoalloxazine. The complexes [(DMA)Cu(PPh 3 ) 2 ](BF 4 )(1), [(DMA)Ru(bpy) 2 ](PF 6 ) 2 (2) and (DMA)WOCl 3 (3) with 1,3-dimethylalloxazine (DMA) were obtained as O 4 -N 5 cheladet species, as evident from an X-ray crystal structure analysis for 3and from spectroscopy (NMR, IR and UV/vis spectroelectrochemistry).DFT and ab initio methodology is used to illustrate the correspondence in spin distribution between the anion radical p systems of alloxazine and isoalloxazine. (en)
Title	Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 . Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 . (en)
skos:prefLabel	Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 . Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 . (en)
skos:notation	RIV/61388955:_____/00:54000176!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	4052;4058
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC D14.20), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	18
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Záliš, Stanislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	717120
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/00:54000176
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	N/A (en)
http://linked.open.../riv/klicoveSlovo	N/A
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[25289B9E9AE0]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20D14.20
http://linked.open...UplatneniVysledku	2000
http://linked.open...v/svazekPeriodika	39
http://linked.open...iv/tvurceVysledku	Fiedler, Jan Kaim, W. Záliš, Stanislav Heilmann, O. Hornung, F. M.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0020-1669
number of pages	7 (xsd:int)

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