About: HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation.     Goto   Sponge   NotDistinct   Permalink

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Description
  • Photolysis of the HCl molecule surface solvated on clusters with two to twelve argon atoms is investigated by means of quantum molecular dynamics simulations.Two basic questions are addressed: i) How does the cage effect change upon increasing the size of the cluster, and ii) How can caging be influenced by an IR excitation of HCl hindered rotation (libration) prior to UV photolysis. The efficiency of caging is discussed in terms of measurable quantities.
  • Photolysis of the HCl molecule surface solvated on clusters with two to twelve argon atoms is investigated by means of quantum molecular dynamics simulations.Two basic questions are addressed: i) How does the cage effect change upon increasing the size of the cluster, and ii) How can caging be influenced by an IR excitation of HCl hindered rotation (libration) prior to UV photolysis. The efficiency of caging is discussed in terms of measurable quantities. (en)
Title
  • HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation.
  • HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation. (en)
skos:prefLabel
  • HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation.
  • HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation. (en)
skos:notation
  • RIV/61388955:_____/00:54000073!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany
  • 10761;10766
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  • P(IAA4040706), Z(AV0Z4040901)
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  • 24
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  • 712275
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  • RIV/61388955:_____/00:54000073
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  • N/A (en)
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  • US - Spojené státy americké
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  • [BE1EC896AF2C]
http://linked.open...i/riv/nazevZdroje
  • Journal of Chemical Physics
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http://linked.open...v/svazekPeriodika
  • 112
http://linked.open...iv/tvurceVysledku
  • Jungwirth, Pavel
  • Slavíček, Petr
  • Ždánská, Petra
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9606
number of pages
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