About: Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I     Goto   Sponge   NotDistinct   Permalink

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  • From extraction experiments and gama-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + 1?Na+ (nb) = 1?M+ (nb) + Na+ (aq) taking place in the two-phase water?nitrobenzene system (M+ = Li+, H3O+, NH4+, Ag+, K+, Rb+, Tl+, Cs+; 1 = barium ionophore I; aq = aqueous phase, nb = nitrobenzene phase) were determined. Furthermore, the stability constants of the 1?M+ complexes in water-saturated nitrobenzene were calculated; they were found to increase in the series of Cs+ { Rb+ { NH4+, K+ { H3O+ { Na+ { Ag+, Tl+ { Li+.
  • From extraction experiments and gama-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + 1?Na+ (nb) = 1?M+ (nb) + Na+ (aq) taking place in the two-phase water?nitrobenzene system (M+ = Li+, H3O+, NH4+, Ag+, K+, Rb+, Tl+, Cs+; 1 = barium ionophore I; aq = aqueous phase, nb = nitrobenzene phase) were determined. Furthermore, the stability constants of the 1?M+ complexes in water-saturated nitrobenzene were calculated; they were found to increase in the series of Cs+ { Rb+ { NH4+, K+ { H3O+ { Na+ { Ag+, Tl+ { Li+. (en)
Title
  • Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I
  • Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I (en)
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  • Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I
  • Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I (en)
skos:notation
  • RIV/60461373:22340/11:43881493!RIV12-MSM-22340___
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  • S, Z(MSM4977751303)
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  • 1
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  • 199102
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  • RIV/60461373:22340/11:43881493
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  • Stability constants; Barium ionophore I; Dicarbollylcobaltate; Nitrobenzene; Extraction; Univalent cations (en)
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  • DE - Spolková republika Německo
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  • [1560E1717D47]
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  • Journal of Radioanalytical and Nuclear Chemistry
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  • 289
http://linked.open...iv/tvurceVysledku
  • Makrlík, Emanuel
  • Vaňura, Petr
http://linked.open...ain/vavai/riv/wos
  • 000291359000004
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issn
  • 0236-5731
number of pages
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  • 10.1007/s10967-011-1043-9
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  • 22340
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