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Description
| - The exchange extraction constants corresponding to the general equilibrium M2+(aq) + SrL2+(nb) ML2+(nb) + Sr2+(aq) occurring in the two- -phase water?nitrobenzene system (Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+; L = tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate; aq = aqueous phase; nb = nitrobenzene phase) were evaluated from extraction experiments and -activity measurements. Furthermore, the stability constants of the ML2+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the cation order Ba2+ < Mn2+ < Pb2+, Co2+ < Cu2+, Zn2+ < Cd2+, Ni2+ < UO22+ < Ca2+.
- The exchange extraction constants corresponding to the general equilibrium M2+(aq) + SrL2+(nb) ML2+(nb) + Sr2+(aq) occurring in the two- -phase water?nitrobenzene system (Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+; L = tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate; aq = aqueous phase; nb = nitrobenzene phase) were evaluated from extraction experiments and -activity measurements. Furthermore, the stability constants of the ML2+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the cation order Ba2+ < Mn2+ < Pb2+, Co2+ < Cu2+, Zn2+ < Cd2+, Ni2+ < UO22+ < Ca2+. (en)
- Na základě extrakčních dat byly stanoveny rovnovážné extrakční konstanty pro reakci M2+(aq) + SrL2+(nb) ML2+(nb) + Sr2+(aq) v systému voda ?nitrobenzen (M2+ = Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ a Ni2+; L = tetra-terc-butyl p-terc-butylkalix[4]aren tetraacetát), aq =vodná fáze; nb = nitrobenzenová fáze). Konstanty stability komplexu ML2+ v nitrobenzenu, nasyceném vodou rostou v řadě Ba2+ < Mn2+ < Pb2+, Co2+ < Cu2+, Zn2+ < Cd2+, Ni2+ < UO22+ < Ca2+. (cs)
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Title
| - Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate
- Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate (en)
- Extrakce Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ a Ni2+ roztokem strontnaté sole dikarbollylkobaltitanu v nitrobenzenu za přítomnosti tetra-terc-butyl p-terc-butylkalix[4]aren tetraacetátu (cs)
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skos:prefLabel
| - Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate
- Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate (en)
- Extrakce Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ a Ni2+ roztokem strontnaté sole dikarbollylkobaltitanu v nitrobenzenu za přítomnosti tetra-terc-butyl p-terc-butylkalix[4]aren tetraacetátu (cs)
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skos:notation
| - RIV/60461373:22340/08:00020720!RIV09-MSM-22340___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA104/05/2667), Z(MSM4977751303), Z(MSM6046137307)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22340/08:00020720
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - divalent cations; calix[4]arene compound; extraction and stability constants; water?nitrobenzene system (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of the Serbian Chemical Society
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Budka, Jan
- Makrlík, E.
- Vaňura, Petr
- Selucký, P.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
of | - Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate
- Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate
- Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate
- Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+,UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate
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