About: Authentication of milk and milk-based foods by direct analysis in real time ionization-high resolution mass spectrometry (DART-HRMS) technique: a critical assessment     Goto   Sponge   NotDistinct   Permalink

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Description
  • The potential of direct analysis in real time (DART) ambient ionization technique coupled with high resolution mass spectrometry (HRMS) in authentication of milk and dairy products was critically assessed. In particular case, DART?HRMS was used for several scenarios: (i) discrimination among milks obtained from various farm animal species (cow, goat, and sheep), (ii) discrimination between cows' milk produced in conventional and organic farming, and, (iii) detection of vegetable oil added to a milk-based product (soft cheese). For this purpose, a rapid profiling procedure based on examination of milk/cheese toluene extracts, was implemented. The obtained triacylglycerol (TAG) profiles (mass spectra) were processed with principal component analysis (PCA) and linear discriminant analysis (LDA). Based on LDA model, reliable differentiation of cows' milk samples and goats'/sheep's milk was possible. The DART?HRMS procedure also allowed distinguishing milk mixtures prepared at adulteration level of 50% (v/v). The capability to recognize milk from conventional and organic farming was rather low, poor classification rates of the LDA model were obtained. On the other hand, reliable detection of the presence of vegetable oils (rapeseed, sunflower, and soybean), added to soft cheese at amount as low as 1% (w/w), was possible. Additionally, the quality of added oil in terms of degree of its oxidation could be documented.
  • The potential of direct analysis in real time (DART) ambient ionization technique coupled with high resolution mass spectrometry (HRMS) in authentication of milk and dairy products was critically assessed. In particular case, DART?HRMS was used for several scenarios: (i) discrimination among milks obtained from various farm animal species (cow, goat, and sheep), (ii) discrimination between cows' milk produced in conventional and organic farming, and, (iii) detection of vegetable oil added to a milk-based product (soft cheese). For this purpose, a rapid profiling procedure based on examination of milk/cheese toluene extracts, was implemented. The obtained triacylglycerol (TAG) profiles (mass spectra) were processed with principal component analysis (PCA) and linear discriminant analysis (LDA). Based on LDA model, reliable differentiation of cows' milk samples and goats'/sheep's milk was possible. The DART?HRMS procedure also allowed distinguishing milk mixtures prepared at adulteration level of 50% (v/v). The capability to recognize milk from conventional and organic farming was rather low, poor classification rates of the LDA model were obtained. On the other hand, reliable detection of the presence of vegetable oils (rapeseed, sunflower, and soybean), added to soft cheese at amount as low as 1% (w/w), was possible. Additionally, the quality of added oil in terms of degree of its oxidation could be documented. (en)
Title
  • Authentication of milk and milk-based foods by direct analysis in real time ionization-high resolution mass spectrometry (DART-HRMS) technique: a critical assessment
  • Authentication of milk and milk-based foods by direct analysis in real time ionization-high resolution mass spectrometry (DART-HRMS) technique: a critical assessment (en)
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  • Authentication of milk and milk-based foods by direct analysis in real time ionization-high resolution mass spectrometry (DART-HRMS) technique: a critical assessment
  • Authentication of milk and milk-based foods by direct analysis in real time ionization-high resolution mass spectrometry (DART-HRMS) technique: a critical assessment (en)
skos:notation
  • RIV/60461373:22330/14:43896665!RIV15-MZE-22330___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(QI91B306)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 4546
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22330/14:43896665
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Mass spectrometry.; Direct analysis in real time; Authenticity; Dairy products; Milk (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • BE - Belgické království
http://linked.open...ontrolniKodProRIV
  • [19B6FF2A9D18]
http://linked.open...i/riv/nazevZdroje
  • Food control
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 36
http://linked.open...iv/tvurceVysledku
  • Hajšlová, Jana
  • Hrbek, Vojtěch
  • Václavík, Lukáš
  • Elich, Ondřej
http://linked.open...ain/vavai/riv/wos
  • 000327363500022
issn
  • 0956-7135
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.foodcont.2013.08.003
http://localhost/t...ganizacniJednotka
  • 22330
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