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rdf:type
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Description
| - In the presence of a Pd catalyst and a base, 6- and 2-iodopurine derivatives undergo reductive C-C dimerization with the formation of the corresponding 6,6´- or 2,2´-dimers. The best results of the dimerization were obtained in the presence of i-Pr2NEt as a base in DMF. Phosphine-free catalysts as well as catalysts containing phosphines can be used. In the presence of catalytic systems containing PPh3 the dimerization does not proceed. This dimerization may become an important side-reaction in the Stille or the Suzuki-Miyaura reactions of iodopurines.
- In the presence of a Pd catalyst and a base, 6- and 2-iodopurine derivatives undergo reductive C-C dimerization with the formation of the corresponding 6,6´- or 2,2´-dimers. The best results of the dimerization were obtained in the presence of i-Pr2NEt as a base in DMF. Phosphine-free catalysts as well as catalysts containing phosphines can be used. In the presence of catalytic systems containing PPh3 the dimerization does not proceed. This dimerization may become an important side-reaction in the Stille or the Suzuki-Miyaura reactions of iodopurines. (en)
- V přítomnosti Pd katalyzátoru a báze podléhají 2- a 6-jodpuriny reduktivní C-C dimerizaci za vzniku odpovídajících 2,2´- a 6,6´-dimerů. (cs)
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Title
| - REDUCTIVE DIMERIZATION of 2- AND 6-IODOPURINES: SIDE REACTION IN Pd-CATALYZED CROSS-COUPLING OF IODOPURINES
- Reduktivní dimerizace 2- a 6-jodpurinů: Vedlejší reakce při Pd katalyzovaných %22cross-coupling%22 reakcích jodopurinů. (cs)
- REDUCTIVE DIMERIZATION of 2- AND 6-IODOPURINES: SIDE REACTION IN Pd-CATALYZED CROSS-COUPLING OF IODOPURINES (en)
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skos:prefLabel
| - REDUCTIVE DIMERIZATION of 2- AND 6-IODOPURINES: SIDE REACTION IN Pd-CATALYZED CROSS-COUPLING OF IODOPURINES
- Reduktivní dimerizace 2- a 6-jodpurinů: Vedlejší reakce při Pd katalyzovaných %22cross-coupling%22 reakcích jodopurinů. (cs)
- REDUCTIVE DIMERIZATION of 2- AND 6-IODOPURINES: SIDE REACTION IN Pd-CATALYZED CROSS-COUPLING OF IODOPURINES (en)
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skos:notation
| - RIV/60461373:22310/07:00018196!RIV08-MSM-22310___
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/06/0888), P(LC06070), Z(MSM6046137301)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22310/07:00018196
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Reductive dimerization; purine; Pd catalysis; cross-coupling (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Collection of Czechoslovak Chemical Communications
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Dvořák, Dalimil
- Tobrman, Tomáš
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
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