About: Novel liquid crystals based on [1]benzothieno[3,2 b][1]benzothiophene     Goto   Sponge   NotDistinct   Permalink

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Description
  • Four series of new [1]benzothieno[3,2-b][1]benzothiophene derivatives have been synthesised. In the non-chiral series SmA phase occurs, while the chiral series exhibits rather wide antiferroelectric SmCA phase just below the SmA phase. The clearing pointis significantly increased when the carbonyl linkage group is used between the heterocyclic core and the alkyl chain. The SmA - SmCA phase transition is studied by DSC and by dielectric spectroscopy, which yields the type of the transition. In the SmCA phase the spontaneous quantities have been measured. The tilt angle shows typical temperature dependence for the phase transition parameter, the values of spontaneous polarisation are rather moderate. The length of the helical pitch increases with increasing length of the non-chiral alkyl chain.
  • Four series of new [1]benzothieno[3,2-b][1]benzothiophene derivatives have been synthesised. In the non-chiral series SmA phase occurs, while the chiral series exhibits rather wide antiferroelectric SmCA phase just below the SmA phase. The clearing pointis significantly increased when the carbonyl linkage group is used between the heterocyclic core and the alkyl chain. The SmA - SmCA phase transition is studied by DSC and by dielectric spectroscopy, which yields the type of the transition. In the SmCA phase the spontaneous quantities have been measured. The tilt angle shows typical temperature dependence for the phase transition parameter, the values of spontaneous polarisation are rather moderate. The length of the helical pitch increases with increasing length of the non-chiral alkyl chain. (en)
Title
  • Novel liquid crystals based on [1]benzothieno[3,2 b][1]benzothiophene
  • Novel liquid crystals based on [1]benzothieno[3,2 b][1]benzothiophene (en)
skos:prefLabel
  • Novel liquid crystals based on [1]benzothieno[3,2 b][1]benzothiophene
  • Novel liquid crystals based on [1]benzothieno[3,2 b][1]benzothiophene (en)
skos:notation
  • RIV/60461373:22310/03:00008080!RIV/2004/GA0/223104/N
http://linked.open.../vavai/riv/strany
  • 603-610
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA106/00/0580), P(GA202/02/0840)
http://linked.open...iv/cisloPeriodika
  • 3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 618430
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/03:00008080
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • antiferroelectric liquid crystals, synthesis, mesomorphic behaviour (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [A4037FBBE064]
http://linked.open...i/riv/nazevZdroje
  • Liq.Cryst.
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 30
http://linked.open...iv/tvurceVysledku
  • Glogarová, Milada
  • Novotná, Vladimíra
  • Svoboda, Jiří
  • Vaněk, Přemysl
  • Kozmík, Václav
  • Košata, Bedřich
issn
  • 0267-8292
number of pages
http://localhost/t...ganizacniJednotka
  • 22310
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