About: Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-N,N-dibutylcarbamoylmethyl phosphine oxide

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About: Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-N,N-dibutylcarbamoylmethyl phosphine oxide Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H(+)B(-)) in the presence of diphenyl-N,Ndibutylcarbamoylmethyl phosphine oxide (DPDBCMPO, L) has been investigated. The equilibrium data have been explained assuming that the species HL(+), HL(2)(+), CaL(2+), CaL(2)(2+), CaL(3)(2+), SrL(2+), SrL(2)(2+), SrL(3)(2+) and SrL(4)(2+) are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the complexes CaL(2+), CaL(2)(2+) and CaL(3)(2+), where L is DPDBCMPO, are somewhat higher than those of the corresponding complex species SrL(2+), SrL(2)(2+) and SrL(3)(2+) Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H(+)B(-)) in the presence of diphenyl-N,Ndibutylcarbamoylmethyl phosphine oxide (DPDBCMPO, L) has been investigated. The equilibrium data have been explained assuming that the species HL(+), HL(2)(+), CaL(2+), CaL(2)(2+), CaL(3)(2+), SrL(2+), SrL(2)(2+), SrL(3)(2+) and SrL(4)(2+) are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the complexes CaL(2+), CaL(2)(2+) and CaL(3)(2+), where L is DPDBCMPO, are somewhat higher than those of the corresponding complex species SrL(2+), SrL(2)(2+) and SrL(3)(2+) (en)
Title	Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-N,N-dibutylcarbamoylmethyl phosphine oxide Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-N,N-dibutylcarbamoylmethyl phosphine oxide (en)
skos:prefLabel	Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-N,N-dibutylcarbamoylmethyl phosphine oxide Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-N,N-dibutylcarbamoylmethyl phosphine oxide (en)
skos:notation	RIV/46356088:_____/11:#0001164!RIV12-MPO-46356088
http://linked.open...avai/predkladatel	ÚJV Řež, a. s.
http://linked.open...avai/riv/aktivita	N S Z
http://linked.open...avai/riv/aktivity	N, S, Z(MSM4977751303)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Selucký, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	ÚJV Řež, a. s.
http://linked.open...dnocenehoVysledku	230551
http://linked.open...ai/riv/idVysledku	RIV/46356088:_____/11:#0001164
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	acidic radioactive-waste; stability-constants; unex process; barium; cesium; tetraacetate; americium (en)
http://linked.open.../riv/klicoveSlovo	cesium americium acidic radioactive-waste barium stability-constants tetraacetate unex process
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[4F0947218F47]
http://linked.open...i/riv/nazevZdroje	Journal of Radioanalytical and Nuclear Chemistry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	287
http://linked.open...iv/tvurceVysledku	Selucký, Pavel
http://linked.open...ain/vavai/riv/wos	000286333400047
http://linked.open...n/vavai/riv/zamer	Predikce poruch heterogenních materiálů, komponent mechanických a biomechanických systémů.
issn	0236-5731
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s10967-010-0680-8

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