About: Extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrgen dicarbollylcobaltate and tetraisopropyl methylene diphosphonate     Goto   Sponge   NotDistinct   Permalink

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  • Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H(+)B(-)) in the presence of tetraisopropyl methylene diphosphonate [T(iPr)MDP, L] has been investigated. The equilibrium data have been explained assuming that the species HL(+), HL(2)(+), ML(2)(2+) and ML(3)(2+) (M(2+) = Ca(2+), Sr(2+)) are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the CaL(n)(2+) complexes, where n = 2, 3 and L is T(iPr)MDP, are somewhat higher than those of the corresponding complex species SrL(n)(.)(2+)
  • Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H(+)B(-)) in the presence of tetraisopropyl methylene diphosphonate [T(iPr)MDP, L] has been investigated. The equilibrium data have been explained assuming that the species HL(+), HL(2)(+), ML(2)(2+) and ML(3)(2+) (M(2+) = Ca(2+), Sr(2+)) are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the CaL(n)(2+) complexes, where n = 2, 3 and L is T(iPr)MDP, are somewhat higher than those of the corresponding complex species SrL(n)(.)(2+) (en)
Title
  • Extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrgen dicarbollylcobaltate and tetraisopropyl methylene diphosphonate
  • Extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrgen dicarbollylcobaltate and tetraisopropyl methylene diphosphonate (en)
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  • Extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrgen dicarbollylcobaltate and tetraisopropyl methylene diphosphonate
  • Extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrgen dicarbollylcobaltate and tetraisopropyl methylene diphosphonate (en)
skos:notation
  • RIV/46356088:_____/11:#0001163!RIV12-MPO-46356088
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • N, S, Z(MSM4977751303)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
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  • 199099
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  • RIV/46356088:_____/11:#0001163
http://linked.open...riv/jazykVysledku
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  • Calcium; Strontium; Extraction; Nitrobenzene; Dicarbollylcobaltate; Tetraisopropyl methylene diphosphonate; Stability constants (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [36D53DEF56DA]
http://linked.open...i/riv/nazevZdroje
  • Journal of Radioanalytical and Nuclear Chemistry
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http://linked.open...v/svazekPeriodika
  • 287
http://linked.open...iv/tvurceVysledku
  • Selucký, Pavel
http://linked.open...ain/vavai/riv/wos
  • 000286333400030
http://linked.open...n/vavai/riv/zamer
issn
  • 0236-5731
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10967-010-0668-4
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