About: Solvent extraction of microamounts of cesium into nitrobenzene using ammonium and thallium dicarbollylcobaltates in the presence of 2,3-naphtho-15-crown-5

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About: Solvent extraction of microamounts of cesium into nitrobenzene using ammonium and thallium dicarbollylcobaltates in the presence of 2,3-naphtho-15-crown-5 Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Extraction of microamounts of cesium by a nitrobenzene solution of ammonium dicarbollylcobaltate (NH(4)(+)B(-)) and thallium dicarbollylcobaltate (Tl(+)B(-)) in the presence of 2,3-naphtho-15-crown-5 (N15C5, L) has been investigated. The equilibrium data have been explained assuming that the complexes ML(+) and ML(2)(+) (M(+) = NH(4)(+); Tl(+); Cs(+)) are present in the organic phase. The stability constants of the ML(+) and ML(2)(+) species (M(+) = NH(4)(+); Tl(+)) in nitrobenzene saturated with water have been determined. It was found that the stability of the complex cations ML(+) and ML(2)(+) (M(+) = NH(4)(+); Tl(+); Cs(+); L = N15C5) in the mentioned medium increases in the Cs(+) < NH(4)(+) < Tl(+) order. Extraction of microamounts of cesium by a nitrobenzene solution of ammonium dicarbollylcobaltate (NH(4)(+)B(-)) and thallium dicarbollylcobaltate (Tl(+)B(-)) in the presence of 2,3-naphtho-15-crown-5 (N15C5, L) has been investigated. The equilibrium data have been explained assuming that the complexes ML(+) and ML(2)(+) (M(+) = NH(4)(+); Tl(+); Cs(+)) are present in the organic phase. The stability constants of the ML(+) and ML(2)(+) species (M(+) = NH(4)(+); Tl(+)) in nitrobenzene saturated with water have been determined. It was found that the stability of the complex cations ML(+) and ML(2)(+) (M(+) = NH(4)(+); Tl(+); Cs(+); L = N15C5) in the mentioned medium increases in the Cs(+) < NH(4)(+) < Tl(+) order. (en)
Title	Solvent extraction of microamounts of cesium into nitrobenzene using ammonium and thallium dicarbollylcobaltates in the presence of 2,3-naphtho-15-crown-5 Solvent extraction of microamounts of cesium into nitrobenzene using ammonium and thallium dicarbollylcobaltates in the presence of 2,3-naphtho-15-crown-5 (en)
skos:prefLabel	Solvent extraction of microamounts of cesium into nitrobenzene using ammonium and thallium dicarbollylcobaltates in the presence of 2,3-naphtho-15-crown-5 Solvent extraction of microamounts of cesium into nitrobenzene using ammonium and thallium dicarbollylcobaltates in the presence of 2,3-naphtho-15-crown-5 (en)
skos:notation	RIV/46356088:_____/09:#0001224!RIV13-GA0-46356088
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(GA104/09/0668), S, Z(MSM4977751303)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Selucký, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	ÚJV Řež, a. s.
http://linked.open...dnocenehoVysledku	342316
http://linked.open...ai/riv/idVysledku	RIV/46356088:_____/09:#0001224
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	extraction; cesium; dicarbollylcobaltate; crown (en)
http://linked.open.../riv/klicoveSlovo	cesium crown extraction dicarbollylcobaltate
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[4624B2FAF202]
http://linked.open...i/riv/nazevZdroje	Journal of Radioanalytical and Nuclear Chemistry
http://linked.open...in/vavai/riv/obor	DL
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Design and development of extractants for radionuclides based on boron cluster anions
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	281
http://linked.open...iv/tvurceVysledku	Selucký, Pavel
http://linked.open...ain/vavai/riv/wos	000270635400031
http://linked.open...n/vavai/riv/zamer	Predikce poruch heterogenních materiálů, komponent mechanických a biomechanických systémů.
issn	0236-5731
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s10967-009-0020-z

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