About: Volumetric behavior of the ternary system benzene-2-methoxy-2-methylbutane-2,2,4-trimethylpentane and all binary sub-systems at temperature range (298.15-318.15) K     Goto   Sponge   NotDistinct   Permalink

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Description
  • Densities of ternary liquid mixtures composed of benzene, 2-methoxy-2-methylbutane (i.e. tert-amyl methyl ether, TAME), and 2,2,4-trimethylpentane (i.e. isooctane, 2,2,4-TMP) are measured at three temperatures 298.15 K, 308.15 K, and 318.15 K at atmospheric pressure by a vibrating-tube densimeter as well as all its binary sub-systems. Excess molar volumes of the mixtures are calculated from the experimental densities and then correlated using the Redlich-Kister equation. The determination of its adjustable parameters is made by the method of least squares. For all studied systems, the positive deviations from ideal behavior are observed at all temperatures. The excess molar volume curves of binary systems differ in the shape and temperature dependence. The experimental binary data are compared with literature data and discussed. The ternary system mentioned above is measured newly. Moreover, the experimental excess molar volumes are compared to the calculation using Peng-Robinson equation with a corrected parameter. The novelty of this work is the prediction of ternary excess molar volumes from binary parameters in Peng-Robinson equation.
  • Densities of ternary liquid mixtures composed of benzene, 2-methoxy-2-methylbutane (i.e. tert-amyl methyl ether, TAME), and 2,2,4-trimethylpentane (i.e. isooctane, 2,2,4-TMP) are measured at three temperatures 298.15 K, 308.15 K, and 318.15 K at atmospheric pressure by a vibrating-tube densimeter as well as all its binary sub-systems. Excess molar volumes of the mixtures are calculated from the experimental densities and then correlated using the Redlich-Kister equation. The determination of its adjustable parameters is made by the method of least squares. For all studied systems, the positive deviations from ideal behavior are observed at all temperatures. The excess molar volume curves of binary systems differ in the shape and temperature dependence. The experimental binary data are compared with literature data and discussed. The ternary system mentioned above is measured newly. Moreover, the experimental excess molar volumes are compared to the calculation using Peng-Robinson equation with a corrected parameter. The novelty of this work is the prediction of ternary excess molar volumes from binary parameters in Peng-Robinson equation. (en)
Title
  • Volumetric behavior of the ternary system benzene-2-methoxy-2-methylbutane-2,2,4-trimethylpentane and all binary sub-systems at temperature range (298.15-318.15) K
  • Volumetric behavior of the ternary system benzene-2-methoxy-2-methylbutane-2,2,4-trimethylpentane and all binary sub-systems at temperature range (298.15-318.15) K (en)
skos:prefLabel
  • Volumetric behavior of the ternary system benzene-2-methoxy-2-methylbutane-2,2,4-trimethylpentane and all binary sub-systems at temperature range (298.15-318.15) K
  • Volumetric behavior of the ternary system benzene-2-methoxy-2-methylbutane-2,2,4-trimethylpentane and all binary sub-systems at temperature range (298.15-318.15) K (en)
skos:notation
  • RIV/44555601:13440/13:43884963!RIV14-GA0-13440___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP108/10/1106)
http://linked.open...iv/cisloPeriodika
  • JAN 15 2013
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 115080
http://linked.open...ai/riv/idVysledku
  • RIV/44555601:13440/13:43884963
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Benzene, 2-Methoxy-2-methylbutane (tert-amyl methyl ether), 2,2,4-Trimethylpentane (isooctane), Density, Vibrating-tube densimeter, Excess molar volume, Correlation, Redlich-Kister equation, Peng-Robinson equation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [158572C06E09]
http://linked.open...i/riv/nazevZdroje
  • Fluid Phase Equilibria
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 337
http://linked.open...iv/tvurceVysledku
  • Kolská, Zdeňka
  • Morávková, Lenka
  • Sedláková, Zuzana
  • Boublík, Tomáš
  • Houšková, Hana
http://linked.open...ain/vavai/riv/wos
  • 000315325500022
issn
  • 0378-3812
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.fluid.2012.09.007
http://localhost/t...ganizacniJednotka
  • 13440
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