About: Synthesis, crystal structure and transport properties of skutterudite-related CoSn1.5Se1.5.     Goto   Sponge   NotDistinct   Permalink

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  • The skutterudite-related phase CoSn1.5Se1.5 has been synthesised and structurally characterized by powder X-ray diffraction data. CoSn1.5Se1.5 display trigonal symmetry, space group RZ3, unit cell parameters a=12.3278(3) A, c=15.1267(6) A, V=1990.8(1) A3 and Z=24. Its crystal structure can be viewed as a modification of the ideal skutterudite structure CoAs3, where the Sn and Se anions order in layers perpendicular to the (111) direction of the skutterudite unit cell. Transport properties of the title compound, which is p-type semiconductor, have been investigated. The thermoelectric figure of merit ZT max was found 0.1 at 600K.
  • The skutterudite-related phase CoSn1.5Se1.5 has been synthesised and structurally characterized by powder X-ray diffraction data. CoSn1.5Se1.5 display trigonal symmetry, space group RZ3, unit cell parameters a=12.3278(3) A, c=15.1267(6) A, V=1990.8(1) A3 and Z=24. Its crystal structure can be viewed as a modification of the ideal skutterudite structure CoAs3, where the Sn and Se anions order in layers perpendicular to the (111) direction of the skutterudite unit cell. Transport properties of the title compound, which is p-type semiconductor, have been investigated. The thermoelectric figure of merit ZT max was found 0.1 at 600K. (en)
Title
  • Synthesis, crystal structure and transport properties of skutterudite-related CoSn1.5Se1.5.
  • Synthesis, crystal structure and transport properties of skutterudite-related CoSn1.5Se1.5. (en)
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  • Synthesis, crystal structure and transport properties of skutterudite-related CoSn1.5Se1.5.
  • Synthesis, crystal structure and transport properties of skutterudite-related CoSn1.5Se1.5. (en)
skos:notation
  • RIV/00216275:25310/09:00008641!RIV12-MSM-25310___
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  • P(GA203/07/0267), V, Z(AV0Z40500505), Z(MSM0021620855), Z(MSM0021627501), Z(MZP0002579801)
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  • RIV/00216275:25310/09:00008641
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  • CoSn1.5Se1.5 (en)
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  • CH - Švýcarská konfederace
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  • [28ACB70F418B]
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  • Journal of Alloys and Compounds
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  • 479
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  • Laufek, František
  • Navrátil, Jiří
  • Plášil, J.
  • Drašar, Čestmír
  • Plecháček, Tomáš
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  • 000267063300039
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  • 0925-8388
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  • 10.1016/j.jallcom.2009.01.067
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  • 25310
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