About: The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents.

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About: The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The organoantimony(III) difluorides containing Y,C,Y chelating, so called pincer, ligands ([2,6-(YCH2)2C6H3]SbF2; Y = MeO, t-BuO and Me2N ) were prepared by the reaction of corresponding dichlorides ([2,6-(YCH2)2C6H3]SbCl2; Y = MeO, t-BuO and Me2N ) with two equivalents of organotin(IV) fluorinating agents Me3SnF or 2-(Me2NCH2)C6H4Sn(n-Bu2)F, respectively. The structure of organonantimony fluorides was determined both in solution by 1H, 13C and 19F NMR spectroscopy and in the solid state using X-ray diffraction. The organoantimony(III) difluorides containing Y,C,Y chelating, so called pincer, ligands ([2,6-(YCH2)2C6H3]SbF2; Y = MeO, t-BuO and Me2N ) were prepared by the reaction of corresponding dichlorides ([2,6-(YCH2)2C6H3]SbCl2; Y = MeO, t-BuO and Me2N ) with two equivalents of organotin(IV) fluorinating agents Me3SnF or 2-(Me2NCH2)C6H4Sn(n-Bu2)F, respectively. The structure of organonantimony fluorides was determined both in solution by 1H, 13C and 19F NMR spectroscopy and in the solid state using X-ray diffraction. (en) The organoantimony(III) difluorides containing Y,C,Y chelating, so called pincer, ligands ([2,6-(YCH2)2C6H3]SbF2; Y = MeO, t-BuO and Me2N ) were prepared by the reaction of corresponding dichlorides ([2,6-(YCH2)2C6H3]SbCl2; Y = MeO, t-BuO and Me2N ) with two equivalents of organotin(IV) fluorinating agents Me3SnF or 2-(Me2NCH2)C6H4Sn(n-Bu2)F, respectively. The structure of organonantimony fluorides was determined both in solution by 1H, 13C and 19F NMR spectroscopy and in the solid state using X-ray diffraction. (cs)
Title	The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. (en) The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. (cs)
skos:prefLabel	The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. (en) The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. (cs)
skos:notation	RIV/00216275:25310/08:00007605!RIV09-GA0-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0468), P(GP203/07/P094), P(LC523), Z(MSM0021620857), Z(MSM0021627501), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Dostál, Libor Růžička, Aleš Jambor, Roman Jirásko, Robert Holeček, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	398793
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/08:00007605
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Antimony; Fluorine; Tin; Chelating ligand; X-ray structure (en)
http://linked.open.../riv/klicoveSlovo	Tin Antimony X-ray structure Chelating ligand Fluorine
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[633594D5239B]
http://linked.open...i/riv/nazevZdroje	Journal of Fluorine Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds Organoantimony(III) and organobismuth(III) compounds containing O,C,O chelating ligands
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	129
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Dostál, Libor Jambor, Roman Růžička, Aleš Jirásko, Robert Holeček, Jaroslav
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures Pokročilé analytické a separační metody a jejich aplikace v diagnostice a technologii živých a neživých materiálů
issn	0022-1139
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents. The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents.

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