About: The novel organolithium O,C,O-pincer compound     Goto   Sponge   NotDistinct   Permalink

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Description
  • The preparation and characterization of organolithium O,C,O-pincer compound [2,6-(tBuOCH2)2C6H3]-Li (1) is described. The X-ray diffraction techniques revealed the dimeric structure of 1 consisting of two lithium atoms Li(1) and Li(2) and two monoanionic chelating aryl ligands in the solid state, where each lithium atom is coordinated by two oxygen atoms of two different ligands. The NMR spectroscopy and cryoscopy measurements established monomer-dimer equilibrium of 1 in concentrated solutions of non-coordinated solvents, while the diluted solutions of 1 consists of monomer only.
  • The preparation and characterization of organolithium O,C,O-pincer compound [2,6-(tBuOCH2)2C6H3]-Li (1) is described. The X-ray diffraction techniques revealed the dimeric structure of 1 consisting of two lithium atoms Li(1) and Li(2) and two monoanionic chelating aryl ligands in the solid state, where each lithium atom is coordinated by two oxygen atoms of two different ligands. The NMR spectroscopy and cryoscopy measurements established monomer-dimer equilibrium of 1 in concentrated solutions of non-coordinated solvents, while the diluted solutions of 1 consists of monomer only. (en)
  • Byla připravena organolithná sloučenina obsahující O,C,O-chelátující ligand. (cs)
Title
  • The novel organolithium O,C,O-pincer compound
  • Organolithná sloučenina obsahující O,C,O-chelátující ligand (cs)
  • The novel organolithium O,C,O-pincer compound (en)
skos:prefLabel
  • The novel organolithium O,C,O-pincer compound
  • Organolithná sloučenina obsahující O,C,O-chelátující ligand (cs)
  • The novel organolithium O,C,O-pincer compound (en)
skos:notation
  • RIV/00216275:25310/05:00003206!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 2422-2426
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/04/0223), P(GA203/99/M037), P(GP203/03/P128), P(LC523)
http://linked.open...iv/cisloPeriodika
  • 7
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 533352
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/05:00003206
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • lithium; O ligand; X ray diffraction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [1EA9C71D4CE3]
http://linked.open...i/riv/nazevZdroje
  • Inorganica Chimica Acta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 358
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Dostál, Libor
  • Jambor, Roman
  • Růžička, Aleš
  • Holeček, Jaroslav
issn
  • 0020-1693
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
is http://linked.open...avai/riv/vysledek of
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