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  • The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity. The first elimination function eliminates the kinetic current ( ) and conserves the diffusion current ( ). The second elimination function eliminates kinetic and charging currents ( and ) simultaneously and conserves the diffusion current ( ). Both functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linea
  • The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity. The first elimination function eliminates the kinetic current ( ) and conserves the diffusion current ( ). The second elimination function eliminates kinetic and charging currents ( and ) simultaneously and conserves the diffusion current ( ). Both functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linea (en)
  • The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity. The first elimination function eliminates the kinetic current ( ) and conserves the diffusion current ( ). The second elimination function eliminates kinetic and charging currents ( and ) simultaneously and conserves the diffusion current ( ). Both functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linea (cs)
Title
  • Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals
  • Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals (en)
  • Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals (cs)
skos:prefLabel
  • Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals
  • Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals (en)
  • Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals (cs)
skos:notation
  • RIV/00216224:14330/99:00005899!RIV08-MSM-14330___
http://linked.open.../vavai/riv/strany
  • 40
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA511/95/1279), P(GV204/97/K084), Z(MSM 143100008), Z(MSM 143100011)
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  • 739870
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  • RIV/00216224:14330/99:00005899
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  • elimination voltammtery (EVLS); elimination of chosen currents; analytical application of EVLS; reduction processes of adenine and cytosine; transfer coefficient (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [CC4D24903526]
http://linked.open...v/mistoKonaniAkce
  • Seč, Czech Republic
http://linked.open...i/riv/mistoVydani
  • Pardubice
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  • Modern Electroanalytical Methods
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Friml, Jiří
  • Trnková, Libuše
  • Dračka, Oldřich
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Univerzita Pardubice
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  • 80-7194-212-X
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  • 14330
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