About: 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline

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About: 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline Goto Sponge NotDistinct Permalink

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Description	Au(III), Co(III) and Rh(III) chloride complexes with pyridine (py), 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) of the general formulae [(MLCl3)-L-1], trans-[(ML4Cl2)-L-2](+), mer-[(ML3Cl3)-L-2], [M-1(LL)Cl-2](+), cis-[M-2(LL)(2)Cl-2](+), where M-1 = Au; M-2 = Co, Rh; L = py; LL = bpy, phen, were studied by H-1-C-13 HMBC and H-1-N-15 HMQC/HSQC. The H-1, C-13 and N-15 coordination shifts (the latter from ca -78 to ca -10 7 ppm) are discussed in relation to the type of metal, electron configuration, coordination sphere geometry and the type of ligand. The C-13 and N-15 chemical shifts were also calculated by quantum-chemical NMR methods, which reproduced well the experimental tendencies concerning the coordination sphere geometry and the ligand type. Au(III), Co(III) and Rh(III) chloride complexes with pyridine (py), 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) of the general formulae [(MLCl3)-L-1], trans-[(ML4Cl2)-L-2](+), mer-[(ML3Cl3)-L-2], [M-1(LL)Cl-2](+), cis-[M-2(LL)(2)Cl-2](+), where M-1 = Au; M-2 = Co, Rh; L = py; LL = bpy, phen, were studied by H-1-C-13 HMBC and H-1-N-15 HMQC/HSQC. The H-1, C-13 and N-15 coordination shifts (the latter from ca -78 to ca -10 7 ppm) are discussed in relation to the type of metal, electron configuration, coordination sphere geometry and the type of ligand. The C-13 and N-15 chemical shifts were also calculated by quantum-chemical NMR methods, which reproduced well the experimental tendencies concerning the coordination sphere geometry and the ligand type. (en)
Title	1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline (en)
skos:prefLabel	1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline (en)
skos:notation	RIV/00216224:14310/07:00022045!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(LC06030), Z(MSM0021622410), Z(MSM0021622413)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Toušek, Jaromír Marek, Radek
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	463135
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/07:00022045
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	quantum chemical NMR calculations (en)
http://linked.open.../riv/klicoveSlovo	quantum chemical NMR calculations
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[F9755D30C9FC]
http://linked.open...i/riv/nazevZdroje	Magnetic Resonance in Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Biomolecular centre
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	45
http://linked.open...iv/tvurceVysledku	Marek, Radek Pazderski, Leszek Toušek, Jaromír Kozerski, Lech Sitkowski, Jerzy Szlyk, Edward
http://linked.open...ain/vavai/riv/wos	000243349900004
http://linked.open...n/vavai/riv/zamer	Proteiny v metabolismu a při interakci organismů s prostředím Physical and chemical properties of advanced materials and structures
issn	0749-1581
number of pages	13 (xsd:int)
http://localhost/t...ganizacniJednotka	14310
is http://linked.open...avai/riv/vysledek of	1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenantroline

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