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Description
| - Oligodeoxynucleotides (ODNs) containing adenines (A), cytosines (C) and guanines (G) are electroactive species and produce cathodic (A,C) and anodic (G) voltammetric peaks at mercury electrodes. The reduction peak potentials of A and C are located very close to each other, so that usually only one voltammetric peak is observed. One signal only can be observed even when adsorptive transfer stripping voltammetry (AdTSV) is used. The elimination voltammetry with linear scan (EVLS) used in connection with a hanging mercury electrode is able to distinguish between A and C signals. The EVLS is based on elimination of one or two selected currents from total currents measured by linear scan voltammetry. The function eliminating kinetic and charging currents, and conserving the diffusion current was calculated for the case of adsorbed electroactive substance, and the theoretical elimination curve has a peak-counterpeak form. Various elimination functions were applied in the analysis of oligonucleotides contain
- Oligodeoxynucleotides (ODNs) containing adenines (A), cytosines (C) and guanines (G) are electroactive species and produce cathodic (A,C) and anodic (G) voltammetric peaks at mercury electrodes. The reduction peak potentials of A and C are located very close to each other, so that usually only one voltammetric peak is observed. One signal only can be observed even when adsorptive transfer stripping voltammetry (AdTSV) is used. The elimination voltammetry with linear scan (EVLS) used in connection with a hanging mercury electrode is able to distinguish between A and C signals. The EVLS is based on elimination of one or two selected currents from total currents measured by linear scan voltammetry. The function eliminating kinetic and charging currents, and conserving the diffusion current was calculated for the case of adsorbed electroactive substance, and the theoretical elimination curve has a peak-counterpeak form. Various elimination functions were applied in the analysis of oligonucleotides contain (en)
- Oligonukleotidy(ODNs) obsahující adenin (A), cytosin (C) a guanin (G) jsou elektroaktivní částice a produkují na rtuťové elektrodě katodické (A,C) a anodické (G) signály. Redukční píky A a C jsou potenciálově lokalizovány tak blízko, že splývají a běžnými elektrochemickými metodami jsme schopni registrovat signál jen jeden. Pomocí eliminační voltametrie s lineární polarizací elektrody(EVLS) se nám podařilo redukční píky A a C nejen rozlišit, ale i dokázat, že v kombinaci EVLS s adsorptvním strippingem lze uvažovat o rozlišení sekvence bází v jednotlivých ODNs. (cs)
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Title
| - Elimination voltammetry of oligonucleotides
- Elimination voltammetry of oligonucleotides (en)
- Eliminační voltametrie oligonukleotidů (cs)
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skos:prefLabel
| - Elimination voltammetry of oligonucleotides
- Elimination voltammetry of oligonucleotides (en)
- Eliminační voltametrie oligonukleotidů (cs)
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skos:notation
| - RIV/00216224:14310/04:00011234!RIV08-AV0-14310___
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/02/0422), P(IAA1163201)
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216224:14310/04:00011234
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Oligonucleotides; elimination voltammetry with linear scan; partial currents; reduction of adenine and cytosine (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...v/mistoKonaniAkce
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http://linked.open...i/riv/mistoVydani
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http://linked.open...i/riv/nazevZdroje
| - Book of Abstracts I - 55th Annual Meeting of the ISE
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...iv/tvurceVysledku
| - Trnková, Libuše
- Jelen, František
- Postbieglová, Irena
- Topinková, Jana
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http://linked.open...vavai/riv/typAkce
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http://linked.open.../riv/zahajeniAkce
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number of pages
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http://purl.org/ne...btex#hasPublisher
| - International Society of Electrochemistry
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http://localhost/t...ganizacniJednotka
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