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  • The electrode reaction mechanism of electrolytical coating by nickel, cobalt and nickel+cobalt on paraffin impregnated graphite electrode was investigated by cyclic voltammetry and elimination voltammetry with linear scan (EVLS). During the electrodeposition of metals on the graphite electrode, hydrogen evolved from aqueous acid solutions decreases cathodic efficiency of the plating process. The elimination of major kinetic current arising due to hydrogen evolution enables one to study the minor processes proceeding at the electrode. Cyclic voltammograms were measured at three scan rates: 12,5 mV/s, 25 mV/s and 50 mV/s and the EVLS functions were calculated for one or two eliminated currents. The results indicate the occurrence of surface reactions with the adsorption of intermediates on graphite. The application of EVLS provides deeper insight into the mechanism of electrode reaction during metal deposition.
  • The electrode reaction mechanism of electrolytical coating by nickel, cobalt and nickel+cobalt on paraffin impregnated graphite electrode was investigated by cyclic voltammetry and elimination voltammetry with linear scan (EVLS). During the electrodeposition of metals on the graphite electrode, hydrogen evolved from aqueous acid solutions decreases cathodic efficiency of the plating process. The elimination of major kinetic current arising due to hydrogen evolution enables one to study the minor processes proceeding at the electrode. Cyclic voltammograms were measured at three scan rates: 12,5 mV/s, 25 mV/s and 50 mV/s and the EVLS functions were calculated for one or two eliminated currents. The results indicate the occurrence of surface reactions with the adsorption of intermediates on graphite. The application of EVLS provides deeper insight into the mechanism of electrode reaction during metal deposition. (en)
  • The electrode reaction mechanism of electrolytical coating by nickel, cobalt and nickel+cobalt on paraffin impregnated graphite electrode was investigated by cyclic voltammetry and elimination voltammetry with linear scan (EVLS). During the electrodeposition of metals on the graphite electrode, hydrogen evolved from aqueous acid solutions decreases cathodic efficiency of the plating process. The elimination of major kinetic current arising due to hydrogen evolution enables one to study the minor processes proceeding at the electrode. Cyclic voltammograms were measured at three scan rates: 12,5 mV/s, 25 mV/s and 50 mV/s and the EVLS functions were calculated for one or two eliminated currents. The results indicate the occurrence of surface reactions with the adsorption of intermediates on graphite. The application of EVLS provides deeper insight into the mechanism of electrode reaction during metal deposition. (cs)
Title
  • Study of electroplating processes on the graphite electrode using elimination voltammetry
  • Study of electroplating processes on the graphite electrode using elimination voltammetry (en)
  • Study of electroplating processes on the graphite electrode using elimination voltammetry (cs)
skos:prefLabel
  • Study of electroplating processes on the graphite electrode using elimination voltammetry
  • Study of electroplating processes on the graphite electrode using elimination voltammetry (en)
  • Study of electroplating processes on the graphite electrode using elimination voltammetry (cs)
skos:notation
  • RIV/00216224:14310/03:00008238!RIV08-AV0-14310___
http://linked.open.../vavai/riv/strany
  • 14-14 V14
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/02/0422), P(IAA1163201)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 629546
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/03:00008238
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Electroplating; paraffin impregnated graphite electrode; Ni; Co; cyclic and elimination voltammetry; mechanism of electrode reaction; adsorption (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [D529F5648E1A]
http://linked.open...v/mistoKonaniAkce
  • Wien, Ostereich
http://linked.open...i/riv/mistoVydani
  • Wien, Ostereich
http://linked.open...i/riv/nazevZdroje
  • 6. Tagung des Arbeitskreises Elektrochemische Analysenmethoden - ELACH 6
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Trnková, Libuše
  • Oriňáková, Renáta
  • Gálová, Miriam
  • Šupicová, Magdaléna
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
number of pages
http://purl.org/ne...btex#hasPublisher
  • Gessellschaft Ostereichischer Chemiker
http://localhost/t...ganizacniJednotka
  • 14310
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