About: Application of carbon electrodes modified with a mercury layer of a different thickness for studies of the adsorption and kinetics of phase transients of cytidine.     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • The kinetics of phase transients of cytidine adsorbed at pyrolytic graphite electrodes, glassy caron electrodes, and the same electrodes modified with a mercury layer (mercury film electrodes)was studied by chronoamperometry (j-t curves and capacitance measurements (C-t curves). In acidic solution (pH 5) the two-dimensional condensation of adsorbed cytidine molecules and formation of a compact layer takes place only in one potential region. In alkaline solution (pH 8.3) cytidine forms two different physisorbed condensed layers at the mercury film electrodes. The phase trasients between the dilute and compact cytidine layers are about three times faster in acid solution than in alkaline solution. As long as the thickness of the mercury layer was greater than 2um, pronounced current maxima characteristic for the nucleation process were observed on j-t curves during phase transients between dilute and compact layers.
  • The kinetics of phase transients of cytidine adsorbed at pyrolytic graphite electrodes, glassy caron electrodes, and the same electrodes modified with a mercury layer (mercury film electrodes)was studied by chronoamperometry (j-t curves and capacitance measurements (C-t curves). In acidic solution (pH 5) the two-dimensional condensation of adsorbed cytidine molecules and formation of a compact layer takes place only in one potential region. In alkaline solution (pH 8.3) cytidine forms two different physisorbed condensed layers at the mercury film electrodes. The phase trasients between the dilute and compact cytidine layers are about three times faster in acid solution than in alkaline solution. As long as the thickness of the mercury layer was greater than 2um, pronounced current maxima characteristic for the nucleation process were observed on j-t curves during phase transients between dilute and compact layers. (en)
  • The kinetics of phase transients of cytidine adsorbed at pyrolytic graphite electrodes, glassy caron electrodes, and the same electrodes modified with a mercury layer (mercury film electrodes)was studied by chronoamperometry (j-t curves and capacitance measurements (C-t curves). In acidic solution (pH 5) the two-dimensional condensation of adsorbed cytidine molecules and formation of a compact layer takes place only in one potential region. In alkaline solution (pH 8.3) cytidine forms two different physisorbed condensed layers at the mercury film electrodes. The phase trasients between the dilute and compact cytidine layers are about three times faster in acid solution than in alkaline solution. As long as the thickness of the mercury layer was greater than 2um, pronounced current maxima characteristic for the nucleation process were observed on j-t curves during phase transients between dilute and compact layers. (cs)
Title
  • Application of carbon electrodes modified with a mercury layer of a different thickness for studies of the adsorption and kinetics of phase transients of cytidine.
  • Application of carbon electrodes modified with a mercury layer of a different thickness for studies of the adsorption and kinetics of phase transients of cytidine. (en)
  • Application of carbon electrodes modified with a mercury layer of a different thickness for studies of the adsorption and kinetics of phase transients of cytidine. (cs)
skos:prefLabel
  • Application of carbon electrodes modified with a mercury layer of a different thickness for studies of the adsorption and kinetics of phase transients of cytidine.
  • Application of carbon electrodes modified with a mercury layer of a different thickness for studies of the adsorption and kinetics of phase transients of cytidine. (en)
  • Application of carbon electrodes modified with a mercury layer of a different thickness for studies of the adsorption and kinetics of phase transients of cytidine. (cs)
skos:notation
  • RIV/00216224:14310/02:00007358!RIV08-AV0-14310___
http://linked.open.../vavai/riv/strany
  • 19
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GV204/97/K084), P(IAA4004002)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 638765
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/02:00007358
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cytidine adlayers; two-dimensional condensation; nucleation and growth; mercury film electrodes; glassy carbon electrodes; pyrolytic graphite electrodes (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [199516EDB02F]
http://linked.open...i/riv/nazevZdroje
  • Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 536
http://linked.open...iv/tvurceVysledku
  • Hasoň, Stanislav
  • Vetterl, Vladimír
issn
  • 0022-0728
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software