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  • Non-conventional electrochemical methods, such as elimination polarography (EP) and elimination voltammetry with linear scan (EVLS) provide the elimination of selected particular currents, forming the measured total current. The most frequently eliminated particular currents are the charging current (Ic), the diffusion current (Id), and the kinetic current (Ik). While the LSV signal of single-stranded DNA at low concentration gives a slight hint in the cathodic process of adenine and cytosine residues, the elimination of Ic and Ik provides quite a clear signal in the form of the peak-counterpeak, which enables the determination of DNA at concentrations below microgram per millilitre. The results received by the adsorptive stripping voltammetry in the mode of linear scan (LSV), square-wave (SWV) and elimination with linear scan (EVLS) are compared and discussed.
  • Non-conventional electrochemical methods, such as elimination polarography (EP) and elimination voltammetry with linear scan (EVLS) provide the elimination of selected particular currents, forming the measured total current. The most frequently eliminated particular currents are the charging current (Ic), the diffusion current (Id), and the kinetic current (Ik). While the LSV signal of single-stranded DNA at low concentration gives a slight hint in the cathodic process of adenine and cytosine residues, the elimination of Ic and Ik provides quite a clear signal in the form of the peak-counterpeak, which enables the determination of DNA at concentrations below microgram per millilitre. The results received by the adsorptive stripping voltammetry in the mode of linear scan (LSV), square-wave (SWV) and elimination with linear scan (EVLS) are compared and discussed. (en)
Title
  • Application of Elimination Methods in Electrochemical Study of DNA
  • Application of Elimination Methods in Electrochemical Study of DNA (en)
skos:prefLabel
  • Application of Elimination Methods in Electrochemical Study of DNA
  • Application of Elimination Methods in Electrochemical Study of DNA (en)
skos:notation
  • RIV/00216224:14310/00:00003961!RIV/2002/MSM/143102/N
http://linked.open.../vavai/riv/strany
  • C-11
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  • P(GV204/97/K084), Z(MSM 143100011)
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  • 704988
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  • RIV/00216224:14310/00:00003961
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  • Elimination Methods, Type of currents, Voltammetry, Adsorption of electroactive substance (en)
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  • [2B31F90541E9]
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  • Brno, Czech Republic
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  • Brno, Czech Republic
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  • Book of Abstracts - DNA Structure and Interactions
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  • Kizek, René
  • Trnková, Libuše
  • Dračka, Oldřich
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http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Biofyzikální ústav AV ČR
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  • 14310
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