About: Experimental evaluation of the influence of saturation media on the mineralogical and physicochemical stability of bentonites     Goto   Sponge   NotDistinct   Permalink

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  • Three bentonite buffer materials (Rokle bentonite, FEBEX bentonite, and Mock-Up-CZ mixture composed of 85% Rokle bentonite, 10% silica sand and 5% graphite) interacted with natural water collected from Josef Underground Educational Facility (UEF) Czech Republic, and four different types of artificial groundwater enriched in K+ and/or Mg2+. The experimental material was prepared in the form of (1) highly compacted samples, (2) dispersion of bentonites (both at temperature of 95 degrees C), (3) drill hole filling during in situ tests at the Josef UEF (at ordinary temperature), and (4) common batch laboratory experiments (at 20 degrees C and at 80-90 degrees C). Partial samples were extracted after 3, 6, 12, and/or 18 months of interaction in the first three set-ups, and after 1 week, 2 weeks, 1 month, 2 months, 3 months, 4 months, 5 months, 7 months, 10 months, and 12 months in the batch experiment. Phase composition and its potential changes were evaluated by X-ray diffraction. In the first three experimental set-ups, no changes were identified. For the batch experiment, formation of illite was detected in FEBEX bentonite saturated with artificial groundwater with K+ concentration of 1083 mg/L By using the same saturation medium, gypsum and/or bassanite formed in the Rokle and FEBEX bentonite. Other media did not affect mineralogical composition. The stability of studied materials was also evaluated by using adsorption and through-diffusion experiments on the basis of migration behaviour of Cs-134. Dispersion of bentonites at laboratory temperature and bentonite samples from in situ test were used as solid phase, and four types of saturation media (artificial groundwater) were used as liquid phase. The distribution coefficient (Kd) is influenced by high concentration of K+ and Mg2+ in saturation media on retention of Cs+. In Rokle bentonite, the increase concentration of K+ and Mg2+ led to a decrease of Kd.
  • Three bentonite buffer materials (Rokle bentonite, FEBEX bentonite, and Mock-Up-CZ mixture composed of 85% Rokle bentonite, 10% silica sand and 5% graphite) interacted with natural water collected from Josef Underground Educational Facility (UEF) Czech Republic, and four different types of artificial groundwater enriched in K+ and/or Mg2+. The experimental material was prepared in the form of (1) highly compacted samples, (2) dispersion of bentonites (both at temperature of 95 degrees C), (3) drill hole filling during in situ tests at the Josef UEF (at ordinary temperature), and (4) common batch laboratory experiments (at 20 degrees C and at 80-90 degrees C). Partial samples were extracted after 3, 6, 12, and/or 18 months of interaction in the first three set-ups, and after 1 week, 2 weeks, 1 month, 2 months, 3 months, 4 months, 5 months, 7 months, 10 months, and 12 months in the batch experiment. Phase composition and its potential changes were evaluated by X-ray diffraction. In the first three experimental set-ups, no changes were identified. For the batch experiment, formation of illite was detected in FEBEX bentonite saturated with artificial groundwater with K+ concentration of 1083 mg/L By using the same saturation medium, gypsum and/or bassanite formed in the Rokle and FEBEX bentonite. Other media did not affect mineralogical composition. The stability of studied materials was also evaluated by using adsorption and through-diffusion experiments on the basis of migration behaviour of Cs-134. Dispersion of bentonites at laboratory temperature and bentonite samples from in situ test were used as solid phase, and four types of saturation media (artificial groundwater) were used as liquid phase. The distribution coefficient (Kd) is influenced by high concentration of K+ and Mg2+ in saturation media on retention of Cs+. In Rokle bentonite, the increase concentration of K+ and Mg2+ led to a decrease of Kd. (en)
Title
  • Experimental evaluation of the influence of saturation media on the mineralogical and physicochemical stability of bentonites
  • Experimental evaluation of the influence of saturation media on the mineralogical and physicochemical stability of bentonites (en)
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  • Experimental evaluation of the influence of saturation media on the mineralogical and physicochemical stability of bentonites
  • Experimental evaluation of the influence of saturation media on the mineralogical and physicochemical stability of bentonites (en)
skos:notation
  • RIV/00216208:11310/13:10193059!RIV14-MSM-11310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, S, Z(MSM0021620855)
http://linked.open...iv/cisloPeriodika
  • DECEMBER
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 74040
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/13:10193059
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Diffusion; Adsorption; Mineralogical changes; Rokle bentonite; FEBEX bentonite (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [91C5A4655413]
http://linked.open...i/riv/nazevZdroje
  • Applied Clay Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 86
http://linked.open...iv/tvurceVysledku
  • Přikryl, Richard
  • Videnska, K.
  • Švandová, Jana
http://linked.open...ain/vavai/riv/wos
  • 000328597100001
http://linked.open...n/vavai/riv/zamer
issn
  • 0169-1317
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.clay.2013.10.002
http://localhost/t...ganizacniJednotka
  • 11310
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