About: Structural and electrochemical studies of Sm@D3h-C74 reveal a weak metal-cage interaction and a small band gap species

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1039/c3nr03447j
Description	A metallofullerene Sm@D3h-C74 that contains a divalent rare-earth metal has been studied structurally and electrochemically. The crystallographic analysis revealed that the endohedral Sm atom is more or less motional rather than being localized at a site where the pyracylene motif is nearby. This suggests a weaker metal-pyracylene interaction in Sm@D3h-C74 relative to that in MII@C74 (M 1/4 Group II metal), thus confirming the importance of the metal variety. The electrochemical studies showed a major difference between the redox properties of Sm@D3h-C74 and other Sm-fullerenes and indicated a small band gap for the title compound. A metallofullerene Sm@D3h-C74 that contains a divalent rare-earth metal has been studied structurally and electrochemically. The crystallographic analysis revealed that the endohedral Sm atom is more or less motional rather than being localized at a site where the pyracylene motif is nearby. This suggests a weaker metal-pyracylene interaction in Sm@D3h-C74 relative to that in MII@C74 (M 1/4 Group II metal), thus confirming the importance of the metal variety. The electrochemical studies showed a major difference between the redox properties of Sm@D3h-C74 and other Sm-fullerenes and indicated a small band gap for the title compound. (en)
Title	Structural and electrochemical studies of Sm@D3h-C74 reveal a weak metal-cage interaction and a small band gap species Structural and electrochemical studies of Sm@D3h-C74 reveal a weak metal-cage interaction and a small band gap species (en)
skos:prefLabel	Structural and electrochemical studies of Sm@D3h-C74 reveal a weak metal-cage interaction and a small band gap species Structural and electrochemical studies of Sm@D3h-C74 reveal a weak metal-cage interaction and a small band gap species (en)
skos:notation	RIV/00216208:11310/13:10159065!RIV14-GA0-11310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	I P Z
http://linked.open...avai/riv/aktivity	I, P(GAP208/10/0179), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	21
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Uhlík, Filip
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	108320
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/13:10159065
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	atom; elucidation; thermochemistry; fullerenes; endohedral metallofullerenes; crystallographic characterization; spectroscopic characterization; site-hopping motion; Sm-containing metallofullerenes (en)
http://linked.open.../riv/klicoveSlovo	thermochemistry atom Sm-containing metallofullerenes crystallographic characterization elucidation endohedral metallofullerenes site-hopping motion spectroscopic characterization fullerenes
http://linked.open...odStatuVydavatele	RU - Ruská federace
http://linked.open...ontrolniKodProRIV	[BEFBC9EC9384]
http://linked.open...i/riv/nazevZdroje	Nanoscale [online]
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Computational studies of nanomaterials based on fullerenes
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	5
http://linked.open...iv/tvurceVysledku	Slanina, Zdeněk Uhlík, Filip Feng, Lai Hao, Yajuan Shi, Zujin Xu, Wei
http://linked.open...ain/vavai/riv/wos	000325762000042
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	2040-3364
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1039/c3nr03447j
http://localhost/t...ganizacniJednotka	11310

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