About: A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface

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About: A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1002/aoc.2987
Description	Mesoporous molecular sieve SBA-15 and conventional silica gel were grafted with 3-[2-(diethylamino)ethylamino]propyl groups and used as supports for the preparation of deposited palladium catalysts, which were subsequently evaluated in Stille cross-coupling reaction of aryl bromides. The highest conversions were achieved with the metal-saturated catalyst resulting from the modified SBA-15. Influence of various reaction parameters (solvent, additive, temperature, etc.) on the overall yield and selectivity was studied. Mesoporous molecular sieve SBA-15 and conventional silica gel were grafted with 3-[2-(diethylamino)ethylamino]propyl groups and used as supports for the preparation of deposited palladium catalysts, which were subsequently evaluated in Stille cross-coupling reaction of aryl bromides. The highest conversions were achieved with the metal-saturated catalyst resulting from the modified SBA-15. Influence of various reaction parameters (solvent, additive, temperature, etc.) on the overall yield and selectivity was studied. (en)
Title	A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface (en)
skos:prefLabel	A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface (en)
skos:notation	RIV/00216208:11310/13:10139219!RIV14-GA0-11310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	I P S
http://linked.open...avai/riv/aktivity	I, P(GA104/09/0561), S
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Semler, Miloslav Štěpnička, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	59096
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/13:10139219
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	TEM measurements; X-ray diffraction; Stille reaction; supported catalysts; palladium (en)
http://linked.open.../riv/klicoveSlovo	Stille reaction TEM measurements X-ray diffraction palladium supported catalysts
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[9BCF374A9A69]
http://linked.open...i/riv/nazevZdroje	Applied Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Supported nanoparticle catalysts for C-C bond forming reactions
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	27
http://linked.open...iv/tvurceVysledku	Čejka, Jiří Štěpnička, Petr Semler, Miloslav
http://linked.open...ain/vavai/riv/wos	000319516500007
issn	0268-2605
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/aoc.2987
http://localhost/t...ganizacniJednotka	11310

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