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  • Complexes of diethylmalonate, a common building block in organic synthesis, with gold(l) and silver(l) have been investigated. Both metal cations coordinate between the two carbonyl-oxygen atoms of diethylmalonate. The gold(I) complex should also bear diethylmalonate in the enol-form in the gas phase, while the diketo form is preferred in the condensed phase. The IRMPD spectrum shows that the diketo form is retained upon electrospray ionization also in the gaseous diethylmalonate complex with Au(PMe3)(+). The diethylmalonate complex with a bare silver cation undergoes an association with a water molecule in the gas phase. Spectra of the bare complex and the water-tagged complex are compared.
  • Complexes of diethylmalonate, a common building block in organic synthesis, with gold(l) and silver(l) have been investigated. Both metal cations coordinate between the two carbonyl-oxygen atoms of diethylmalonate. The gold(I) complex should also bear diethylmalonate in the enol-form in the gas phase, while the diketo form is preferred in the condensed phase. The IRMPD spectrum shows that the diketo form is retained upon electrospray ionization also in the gaseous diethylmalonate complex with Au(PMe3)(+). The diethylmalonate complex with a bare silver cation undergoes an association with a water molecule in the gas phase. Spectra of the bare complex and the water-tagged complex are compared. (en)
Title
  • Silver(I) and gold(I) complexes of diethylmalonate
  • Silver(I) and gold(I) complexes of diethylmalonate (en)
skos:prefLabel
  • Silver(I) and gold(I) complexes of diethylmalonate
  • Silver(I) and gold(I) complexes of diethylmalonate (en)
skos:notation
  • RIV/00216208:11310/12:10133128!RIV13-GA0-11310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP207/11/0338), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 330
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
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  • 167871
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/12:10133128
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • water tagging; silver; malonate; keto-enol tautomerism; spectroscopy; infrared multiphoton dissociation; gold (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [7BC68B58429F]
http://linked.open...i/riv/nazevZdroje
  • International Journal of Mass Spectrometry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2012
http://linked.open...iv/tvurceVysledku
  • Roithová, Jana
  • Jašíková, Lucie
  • Škríba, Anton
http://linked.open...ain/vavai/riv/wos
  • 000312745900029
http://linked.open...n/vavai/riv/zamer
issn
  • 1387-3806
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.ijms.2012.08.019
http://localhost/t...ganizacniJednotka
  • 11310
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