About: Polyacetylene-Type Networks Prepared by Coordination Polymerization of Diethynylarenes: New Type of Microporous Organic Polymers

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Polyacetylene-Type Networks Prepared by Coordination Polymerization of Diethynylarenes: New Type of Microporous Organic Polymers Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1002/marc.201100599
Description	Microporous organic polymers (MOP) of a new type have been synthesised in high yields by a simple coordination polymerization of 1,3-diethynylbenzene, 1,4-diethynylbenzene and 4,4'-diethynylbiphenyl catalysed by [Rh(cod)acac] and [Rh(nbd)acac] complexes. The new MOPs are non-swellable polyacetylene-type conjugated networks consisting of ethynylaryl-substituted polyene main chains that are crosslinked by arylene linkers. Prepared MOP samples have a mole fraction of branching units (by 13C CP/MAS NMR) from 0.30 to 0.47 and exhibit the BET (Brunaer-Emmett-Teller) surface up to 809 m2 g-1 and hydrogen uptake up to 0.69 wt% (77 K, H2 pressure 750 torr). Microporous organic polymers (MOP) of a new type have been synthesised in high yields by a simple coordination polymerization of 1,3-diethynylbenzene, 1,4-diethynylbenzene and 4,4'-diethynylbiphenyl catalysed by [Rh(cod)acac] and [Rh(nbd)acac] complexes. The new MOPs are non-swellable polyacetylene-type conjugated networks consisting of ethynylaryl-substituted polyene main chains that are crosslinked by arylene linkers. Prepared MOP samples have a mole fraction of branching units (by 13C CP/MAS NMR) from 0.30 to 0.47 and exhibit the BET (Brunaer-Emmett-Teller) surface up to 809 m2 g-1 and hydrogen uptake up to 0.69 wt% (77 K, H2 pressure 750 torr). (en)
Title	Polyacetylene-Type Networks Prepared by Coordination Polymerization of Diethynylarenes: New Type of Microporous Organic Polymers Polyacetylene-Type Networks Prepared by Coordination Polymerization of Diethynylarenes: New Type of Microporous Organic Polymers (en)
skos:prefLabel	Polyacetylene-Type Networks Prepared by Coordination Polymerization of Diethynylarenes: New Type of Microporous Organic Polymers Polyacetylene-Type Networks Prepared by Coordination Polymerization of Diethynylarenes: New Type of Microporous Organic Polymers (en)
skos:notation	RIV/00216208:11310/12:10120355!RIV13-GA0-11310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	I P S Z
http://linked.open...avai/riv/aktivity	I, P(GA203/08/0604), P(GAP108/11/1661), P(GD203/08/H032), S, Z(AV0Z40400503), Z(AV0Z40500505), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Vohlídal, Jiří Zedník, Jiří Sedláček, Jan Hanková, Vladimíra Sivkova, Radoslava Parusheva Slováková, Eva
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	159527
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/12:10120355
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	hydrogen storage; conjugated polymers; adsorption (en)
http://linked.open.../riv/klicoveSlovo	conjugated polymers adsorption hydrogen storage
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[74E3B9A1B6EF]
http://linked.open...i/riv/nazevZdroje	Macromolecular Rapid Communications
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	6 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...vavai/riv/projekt	Organic nanoporous polymers derived from arylacetylenes as materials for hydrogen storage Advanced molecular sieves for capture and storage of CO2 and H2 Advanced catalytic processes and materials
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	33
http://linked.open...iv/tvurceVysledku	Sedláček, Jan Vohlídal, Jiří Zukal, Arnošt Balcar, Hynek Brus, Jiří Slováková, Eva Zedník, Jiří Hanková, Vladimíra Sivkova, Radoslava Parusheva
http://linked.open...ain/vavai/riv/wos	000299102700009
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1022-1336
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/marc.201100599
http://localhost/t...ganizacniJednotka	11310
is http://linked.open...avai/riv/vysledek of	Polyacetylene-Type Networks Prepared by Coordination Polymerization of Diethynylarenes: New Type of Microporous Organic Polymers

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software