About: Polarographic and voltammetric determination of genotoxic 2-aminofluoren-9-one at mercury electrodes     Goto   Sponge   NotDistinct   Permalink

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  • Electrochemical behavior of genotoxic 2-aminofluoren-9-one (2-AFN) was investigated by DC tast polarography (DCTP) and differential pulse polarography (DPP), both at a classical dropping mercury electrode (DME), and by DC voltammetry (DCV), differential pulse voltammetry (DPV), and adsorptive stripping differential pulse voltammetry (AdSDPV), all at a miniaturized hanging mercury drop minielectrode (HMDmE), in buffered aqueous-methanolic solutions. Optimum conditions were found for the determination of 2-AFN by DCTP at DME in the concentration range from 1 x 10-6 to 1 x 10-4 mol l-1 (with a limit of quantification (LQ) of 5 x 10-7 mol l-1), by DPP at DME (from 1 x 10-7 to 1 x 10-4 mol l-1; LQ on level of 1 x 10-7 mol l-1), by DCV and DPV at HMDmE (both from 1 x 10-7 to 1 x 10-4 mol l-1; LQs on level of 2 x 10-7 and 1 x 10-7 mol l-1 for DCV and DPV, respectively), and by AdSDPV at HMDmE (from 2 x 10-9 to 1 x 10-7 mol l-1; LQ ALMOST EQUAL TO 4 x 10-9 mol l-1). Practical applicability of the developed methods was verified on the direct determination of 2-AFN in model samples of drinking and river water in nanomolar to micromolar concentrations.
  • Electrochemical behavior of genotoxic 2-aminofluoren-9-one (2-AFN) was investigated by DC tast polarography (DCTP) and differential pulse polarography (DPP), both at a classical dropping mercury electrode (DME), and by DC voltammetry (DCV), differential pulse voltammetry (DPV), and adsorptive stripping differential pulse voltammetry (AdSDPV), all at a miniaturized hanging mercury drop minielectrode (HMDmE), in buffered aqueous-methanolic solutions. Optimum conditions were found for the determination of 2-AFN by DCTP at DME in the concentration range from 1 x 10-6 to 1 x 10-4 mol l-1 (with a limit of quantification (LQ) of 5 x 10-7 mol l-1), by DPP at DME (from 1 x 10-7 to 1 x 10-4 mol l-1; LQ on level of 1 x 10-7 mol l-1), by DCV and DPV at HMDmE (both from 1 x 10-7 to 1 x 10-4 mol l-1; LQs on level of 2 x 10-7 and 1 x 10-7 mol l-1 for DCV and DPV, respectively), and by AdSDPV at HMDmE (from 2 x 10-9 to 1 x 10-7 mol l-1; LQ ALMOST EQUAL TO 4 x 10-9 mol l-1). Practical applicability of the developed methods was verified on the direct determination of 2-AFN in model samples of drinking and river water in nanomolar to micromolar concentrations. (en)
Title
  • Polarographic and voltammetric determination of genotoxic 2-aminofluoren-9-one at mercury electrodes
  • Polarographic and voltammetric determination of genotoxic 2-aminofluoren-9-one at mercury electrodes (en)
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  • Polarographic and voltammetric determination of genotoxic 2-aminofluoren-9-one at mercury electrodes
  • Polarographic and voltammetric determination of genotoxic 2-aminofluoren-9-one at mercury electrodes (en)
skos:notation
  • RIV/00216208:11310/11:10105663!RIV12-TA0-11310___
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  • P(LC06035), P(ME10004), P(TA01020565), S, Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 12
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  • 221068
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  • RIV/00216208:11310/11:10105663
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  • Spiked water samples; 2-Aminofluoren-9-one; Mercury electrodes; Voltammetry; Polarography; Electrochemistry; Analytical methods (en)
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  • CZ - Česká republika
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  • [9FFC65F85C51]
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  • Collection of Czechoslovak Chemical Communications
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  • 76
http://linked.open...iv/tvurceVysledku
  • Barek, Jiří
  • Daňhel, Aleš
  • Hájková, Andrea
  • Vyskočil, Vlastimil
  • Wang, Joseph
http://linked.open...ain/vavai/riv/wos
  • 000299816100023
http://linked.open...n/vavai/riv/zamer
issn
  • 0010-0765
number of pages
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  • 10.1135/cccc2011142
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  • 11310
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