About: Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands     Goto   Sponge   NotDistinct   Permalink

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Description
  • Two polar phosphinoferrocene ligands, 1'-(diphenylphosphino)ferrocene-1-carboxamide (1) and 1'-(diphenylphosphino)ferrocene-1-carbohydrazide (2), were synthesized in good yields from 1'-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) via the reactive benzotriazole derivative, 1-[1'-(diphenylphosphino)ferrocene-1-carbonyl]-1H-1,2,3-benzotriazole (3). The hydrazide was further converted via standard condensation reactions to three phosphinoferrocene heterocycles, viz 2-[1'-(diphenylphosphino)ferrocen-1-yl]-1,3,4-oxadiazole (4), 1-[1'-(diphenylphosphino)ferrocen-1-carbonyl]-3,5-dimethyl-1,2-pyrazole (5), and 1-[1'-(diphenylphosphino)ferrocene-1-carboxamido]-3,5-dimethylpyrrole (6). These compounds have been structurally characterized and studied as ligands in palladium(II) complexes.
  • Two polar phosphinoferrocene ligands, 1'-(diphenylphosphino)ferrocene-1-carboxamide (1) and 1'-(diphenylphosphino)ferrocene-1-carbohydrazide (2), were synthesized in good yields from 1'-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) via the reactive benzotriazole derivative, 1-[1'-(diphenylphosphino)ferrocene-1-carbonyl]-1H-1,2,3-benzotriazole (3). The hydrazide was further converted via standard condensation reactions to three phosphinoferrocene heterocycles, viz 2-[1'-(diphenylphosphino)ferrocen-1-yl]-1,3,4-oxadiazole (4), 1-[1'-(diphenylphosphino)ferrocen-1-carbonyl]-3,5-dimethyl-1,2-pyrazole (5), and 1-[1'-(diphenylphosphino)ferrocene-1-carboxamido]-3,5-dimethylpyrrole (6). These compounds have been structurally characterized and studied as ligands in palladium(II) complexes. (en)
Title
  • Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands
  • Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands (en)
skos:prefLabel
  • Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands
  • Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands (en)
skos:notation
  • RIV/00216208:11310/11:10101066!RIV12-MSM-11310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • S, Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 23
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  • 233885
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  • RIV/00216208:11310/11:10101066
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  • Structure elucidation; Palladium complexes; Heterocycles; Hydrazides; Amides; Phosphines; Ferrocene (en)
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  • NL - Nizozemsko
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  • [63DC6C17B6C1]
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  • Journal of Organometallic Chemistry
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  • 696
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Štěpnička, Petr
  • Solařová, Hana
http://linked.open...ain/vavai/riv/wos
  • 000296551400021
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-328X
number of pages
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  • 10.1016/j.jorganchem.2011.08.043
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  • 11310
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