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Description
| - This work demonstrates that low antimicrobial toxicity C2-substituted imidazolium-based ILs, with either ester or amide groups in the side chain, can successfully replace harmful volatile organic compounds (VOCs) in the asymmetric carbonyl-ene reaction of phenylglyoxal with four alkenes catalysed by {[(R)-BINAP]Pd}(SbF6)2. Furthermore, the Pd(II) catalyst immobilised in these ILs was recycled and reused up to 5 times without loss of enantioselectivity, although a decrease in yield was observed.
- This work demonstrates that low antimicrobial toxicity C2-substituted imidazolium-based ILs, with either ester or amide groups in the side chain, can successfully replace harmful volatile organic compounds (VOCs) in the asymmetric carbonyl-ene reaction of phenylglyoxal with four alkenes catalysed by {[(R)-BINAP]Pd}(SbF6)2. Furthermore, the Pd(II) catalyst immobilised in these ILs was recycled and reused up to 5 times without loss of enantioselectivity, although a decrease in yield was observed. (en)
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Title
| - Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal
- Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal (en)
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skos:prefLabel
| - Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal
- Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal (en)
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skos:notation
| - RIV/00216208:11160/14:10292854!RIV15-MSM-11160___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216208:11160/14:10292854
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - ionic liquids; carbonyl-ene reaction; asymmetric catalysis; antimicrobial toxicity (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - AE - Stát Spojené arabské emiráty
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Gathergood, Nicholas
- Špulák, Marcel
- Connon, Stephen J.
- Gore, Rohitkumar G.
- Truong, Thi-Kim-Thu
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.2174/2213346101666140421220156
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http://localhost/t...ganizacniJednotka
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