About: Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal     Goto   Sponge   NotDistinct   Permalink

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Description
  • This work demonstrates that low antimicrobial toxicity C2-substituted imidazolium-based ILs, with either ester or amide groups in the side chain, can successfully replace harmful volatile organic compounds (VOCs) in the asymmetric carbonyl-ene reaction of phenylglyoxal with four alkenes catalysed by {[(R)-BINAP]Pd}(SbF6)2. Furthermore, the Pd(II) catalyst immobilised in these ILs was recycled and reused up to 5 times without loss of enantioselectivity, although a decrease in yield was observed.
  • This work demonstrates that low antimicrobial toxicity C2-substituted imidazolium-based ILs, with either ester or amide groups in the side chain, can successfully replace harmful volatile organic compounds (VOCs) in the asymmetric carbonyl-ene reaction of phenylglyoxal with four alkenes catalysed by {[(R)-BINAP]Pd}(SbF6)2. Furthermore, the Pd(II) catalyst immobilised in these ILs was recycled and reused up to 5 times without loss of enantioselectivity, although a decrease in yield was observed. (en)
Title
  • Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal
  • Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal (en)
skos:prefLabel
  • Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal
  • Low Antimicrobial Toxicity Ionic Liquids: Solvents for Asymmetric Carbonyl-Ene Reactions of Phenylglyoxal (en)
skos:notation
  • RIV/00216208:11160/14:10292854!RIV15-MSM-11160___
http://linked.open...avai/riv/aktivita
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  • I, P(GAP207/10/2048)
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  • 3
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  • 26656
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  • RIV/00216208:11160/14:10292854
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  • ionic liquids; carbonyl-ene reaction; asymmetric catalysis; antimicrobial toxicity (en)
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  • AE - Stát Spojené arabské emiráty
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  • [F4355AC126D4]
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  • Current Green Chemistry
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  • 1
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  • Gathergood, Nicholas
  • Špulák, Marcel
  • Connon, Stephen J.
  • Gore, Rohitkumar G.
  • Truong, Thi-Kim-Thu
issn
  • 2213-3461
number of pages
http://bibframe.org/vocab/doi
  • 10.2174/2213346101666140421220156
http://localhost/t...ganizacniJednotka
  • 11160
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