About: Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes     Goto   Sponge   NotDistinct   Permalink

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Description
  • Ionic liquids with natural organic derived anions (L-lactate, L-tartrate, malonate, succinate, L-malate, pyruvate, D-glucuronate, D-galacturonate) were easily prepared from tetrabutylammonium hydroxide and an excess of the corresponding acid with good yields. Their characterization was realized through classical NMR, IR, and elemental analysis techniques; their viscosity and TGA (thermogravimetric analysis) parameters were also determined. These ionic liquids showed good performance and recyclability in the selective catalytic hydrogenation of 1,5-cyclooctadiene (1,5-COD) into cyclooctene (COD) at room temperature under atmospheric H-2 pressure. Antimicrobial toxicity assays toward a large panel of bacteria and fungi strains were also completed and biodegradation studies (Closed Bottle test, 28 days) were also performed.
  • Ionic liquids with natural organic derived anions (L-lactate, L-tartrate, malonate, succinate, L-malate, pyruvate, D-glucuronate, D-galacturonate) were easily prepared from tetrabutylammonium hydroxide and an excess of the corresponding acid with good yields. Their characterization was realized through classical NMR, IR, and elemental analysis techniques; their viscosity and TGA (thermogravimetric analysis) parameters were also determined. These ionic liquids showed good performance and recyclability in the selective catalytic hydrogenation of 1,5-cyclooctadiene (1,5-COD) into cyclooctene (COD) at room temperature under atmospheric H-2 pressure. Antimicrobial toxicity assays toward a large panel of bacteria and fungi strains were also completed and biodegradation studies (Closed Bottle test, 28 days) were also performed. (en)
Title
  • Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes
  • Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes (en)
skos:prefLabel
  • Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes
  • Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes (en)
skos:notation
  • RIV/00216208:11160/13:10145915!RIV14-GA0-11160___
http://linked.open...avai/predkladatel
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  • I, P(GAP207/10/2048)
http://linked.open...iv/cisloPeriodika
  • 30
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  • 63497
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  • RIV/00216208:11160/13:10145915
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  • Biodegradation; Toxicity; Hydrogenation; Characterization; Synthesis; Ionic liquids (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [CAFDAC6D4341]
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  • Tetrahedron
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  • 69
http://linked.open...iv/tvurceVysledku
  • Gathergood, Nicholas
  • Špulák, Marcel
  • Beadham, Ian
  • Bouquillon, Sandrine
  • Courty, Matthieu
  • Ferlin, Nadege
  • Gatard, Sylvain
  • Ghavre, Mukund
  • Haiss, Annette
  • Kuemmerer, Klaus
  • Quilty, Brid
http://linked.open...ain/vavai/riv/wos
  • 000321474100019
issn
  • 0040-4020
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tet.2013.05.054
http://localhost/t...ganizacniJednotka
  • 11160
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