About: Direct coupling of supported liquid membrane extractions to capillary electrophoresis. Sensitivity enhancement in analyses of untreated complex samples     Goto   Sponge   NotDistinct   Permalink

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Description
  • Extractions across supported liquid membrane (SLM) were in-line coupled to capillary electrophoresis (CE) commercial system for direct injection of basic drugs from raw complex samples. A micro-extraction unit was inserted into the CE system sampling device and ensured excellent sample clean-up and injections directly from the membrane surface. Transient isotachophoresis (t-ITP) combined with large electrokinetic injections of selectively extracted basic analytes increased the sensitivity of the analytical method up to 300-fold when compared with conventional hydrodynamic injections and capillary zone electrophoresis (CZE) of the basic analytes.
  • Extractions across supported liquid membrane (SLM) were in-line coupled to capillary electrophoresis (CE) commercial system for direct injection of basic drugs from raw complex samples. A micro-extraction unit was inserted into the CE system sampling device and ensured excellent sample clean-up and injections directly from the membrane surface. Transient isotachophoresis (t-ITP) combined with large electrokinetic injections of selectively extracted basic analytes increased the sensitivity of the analytical method up to 300-fold when compared with conventional hydrodynamic injections and capillary zone electrophoresis (CZE) of the basic analytes. (en)
Title
  • Direct coupling of supported liquid membrane extractions to capillary electrophoresis. Sensitivity enhancement in analyses of untreated complex samples
  • Direct coupling of supported liquid membrane extractions to capillary electrophoresis. Sensitivity enhancement in analyses of untreated complex samples (en)
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  • Direct coupling of supported liquid membrane extractions to capillary electrophoresis. Sensitivity enhancement in analyses of untreated complex samples
  • Direct coupling of supported liquid membrane extractions to capillary electrophoresis. Sensitivity enhancement in analyses of untreated complex samples (en)
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  • RIV/68081715:_____/14:00438019!RIV15-GA0-68081715
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  • I, P(GA13-05762S)
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  • 11638
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  • RIV/68081715:_____/14:00438019
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  • capillary electrophoresis; supported liquid membrane; transient isotachophoresis (en)
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  • [905BCEB1B802]
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  • Brno
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  • Brno
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  • CECE 2014. 11th International Interdisciplinary Meeting on Bioanalysis
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  • Boček, Petr
  • Kubáň, Pavel
  • Pantůčková, Pavla
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number of pages
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  • Ústav analytické chemie AV ČR
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  • 978-80-904959-2-0
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