About: Properties of moving boundaries in electrophoretic systems with multivalent weak electrolytes: principles of non-Kohlrausch concentration adjustment.

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Description	The properties of electrophoretic moving boundaries were studied in systems containing multivalent weak electrolytes where the Kohlrausch regulating law is not valid. It was shown that zones of unexpected properties can be formed in such systems and that the adjusted concentrations in these zones cannot be predicted using present knowledge. A theoretical approach to the properties of such “non-Kohlrausch” systems was presented that allows the explanation and prediction of their properties: their adjusted concentrations are function of the composition of both zones that formed the original boundary. The theory is illustrated and verified by both computer simulations and experiments. The properties of electrophoretic moving boundaries were studied in systems containing multivalent weak electrolytes where the Kohlrausch regulating law is not valid. It was shown that zones of unexpected properties can be formed in such systems and that the adjusted concentrations in these zones cannot be predicted using present knowledge. A theoretical approach to the properties of such “non-Kohlrausch” systems was presented that allows the explanation and prediction of their properties: their adjusted concentrations are function of the composition of both zones that formed the original boundary. The theory is illustrated and verified by both computer simulations and experiments. (en) Byly studovány vlastnosti elektroforetických rozhraní v systémech tvořených vícesytnými slabými elektrolyty, ve kterých neplatí Kohlrauschův regulační princip. Bylo ukázáno, že v takových systémech mohou vznikat zóny, jejichž vlastnosti a složení nelze vysvětlit na základě dosud používaných principů. Byl vypracován teoretický model umožňující předpovídat vlastnosti zón a rozhraní v takovýchto “nekohlrauschovských” systémech, kdy vlastnosti nově vytvořené adjustované zóny jsou funkcí vlastností obou původních zón, mezi kterými se nová zóna vytvořila. Počítačové simulace a experimenty pro vybrané modelové systémy jsou v souladu s předloženou teorií. (cs)
Title	Properties of moving boundaries in electrophoretic systems with multivalent weak electrolytes: principles of non-Kohlrausch concentration adjustment. Properties of moving boundaries in electrophoretic systems with multivalent weak electrolytes: principles of non-Kohlrausch concentration adjustment. (en) Vlastnosti pohyblivých rozhraní v elektroforetických systémech s vícemocnými slabými elektrolyty: principy nekohlrauschovské adjustace koncentrací (cs)
skos:prefLabel	Properties of moving boundaries in electrophoretic systems with multivalent weak electrolytes: principles of non-Kohlrausch concentration adjustment. Properties of moving boundaries in electrophoretic systems with multivalent weak electrolytes: principles of non-Kohlrausch concentration adjustment. (en) Vlastnosti pohyblivých rozhraní v elektroforetických systémech s vícemocnými slabými elektrolyty: principy nekohlrauschovské adjustace koncentrací (cs)
skos:notation	RIV/68081715:_____/06:00049276!RIV07-AV0-68081715
http://linked.open.../vavai/riv/strany	4601;4609
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/05/2106), P(IAA400310609), P(IAA4031401), Z(AV0Z40310501)
http://linked.open...iv/cisloPeriodika	23
http://linked.open...vai/riv/dodaniDat	2007
http://linked.open...aciTvurceVysledku	Gebauer, Petr Malá, Zdeňka
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav analytické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	495587
http://linked.open...ai/riv/idVysledku	RIV/68081715:_____/06:00049276
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Kohlrausch; moving boundaries; multivalent weak electrolytes (en)
http://linked.open.../riv/klicoveSlovo	Kohlrausch moving boundaries multivalent weak electrolytes
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[176DCF978AA4]
http://linked.open...i/riv/nazevZdroje	Electrophoresis
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Modern instrumentation in chemical, food and clinical analysis Sample induced electromigration phenomena in capillary electrophoresis Development ov new optimizing and methodological techniques for capillary electrophoresis
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	27
http://linked.open...iv/tvurceVysledku	Malá, Zdeňka Gebauer, Petr
http://linked.open...n/vavai/riv/zamer	Moderní analytické techniky pro bioanalýzu, ekologii a nanotechnologie
issn	0173-0835
number of pages	9 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Properties of moving boundaries in electrophoretic systems with multivalent weak electrolytes: principles of non-Kohlrausch concentration adjustment. Properties of moving boundaries in electrophoretic systems with multivalent weak electrolytes: principles of non-Kohlrausch concentration adjustment.

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