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  • During the last years, several authors have focused on the characterization of the size and charge of the nanoparticles by capillary electrophoresis. However, considering that nanoparticles are generally suspended in a solvent different from those commonly used as background electrolytes (BGE), an appropriate characterization of the behavior of the nanoparticles in the sample-BGE interface is required, as this might affect the overall electrophoretic behavior of the nanoparticles. In the present work, we address the evaluation,of the behavior of COOH-coated maghemite nanoparticles in the vicinity of a pH boundary. To do so, different suspensions of nanoparticles prepared in acid media were injected into a borate/NaOH pH 9.5 BGE. The formation and evolution of boundaries in the sample-BGE interface in such systems was modeled by computer simulation. A systematic evaluation of the effect that parameters such as the co-ion, the sample pH or the injection time have on the electrophoretic behavior of the nanoparticles was carried out.
  • During the last years, several authors have focused on the characterization of the size and charge of the nanoparticles by capillary electrophoresis. However, considering that nanoparticles are generally suspended in a solvent different from those commonly used as background electrolytes (BGE), an appropriate characterization of the behavior of the nanoparticles in the sample-BGE interface is required, as this might affect the overall electrophoretic behavior of the nanoparticles. In the present work, we address the evaluation,of the behavior of COOH-coated maghemite nanoparticles in the vicinity of a pH boundary. To do so, different suspensions of nanoparticles prepared in acid media were injected into a borate/NaOH pH 9.5 BGE. The formation and evolution of boundaries in the sample-BGE interface in such systems was modeled by computer simulation. A systematic evaluation of the effect that parameters such as the co-ion, the sample pH or the injection time have on the electrophoretic behavior of the nanoparticles was carried out. (en)
Title
  • Study of behavior of carboxylic magnetite core shell nanoparticles on a pH boundary
  • Study of behavior of carboxylic magnetite core shell nanoparticles on a pH boundary (en)
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  • Study of behavior of carboxylic magnetite core shell nanoparticles on a pH boundary
  • Study of behavior of carboxylic magnetite core shell nanoparticles on a pH boundary (en)
skos:notation
  • RIV/61989592:15310/14:33151653!RIV15-MSM-15310___
http://linked.open...avai/riv/aktivita
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  • P(ED2.1.00/03.0058), P(EE2.3.20.0018), P(EE2.3.30.0004)
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  • OCT
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  • 48232
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  • RIV/61989592:15310/14:33151653
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  • pH boundary; Dynamic pH junction; Boundary effects; Stacking; Nanopartides (en)
http://linked.open.../riv/klicoveSlovo
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  • NL - Nizozemsko
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  • [2F4F837F0B7D]
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  • Journal of Chromatography A: Symposium Volumes
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  • 1364
http://linked.open...iv/tvurceVysledku
  • Petr, Jan
  • Zbořil, Radek
  • Ševčík, Juraj
  • Marková, Zdenka
  • Cacho, Carmen
http://linked.open...ain/vavai/riv/wos
  • 000343359200008
issn
  • 0021-9673
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.chroma.2014.08.090
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  • 15310
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