About: Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands     Goto   Sponge   NotDistinct   Permalink

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  • A series of Ni(II) dithiolenes derived from maleonitriledithiol (mnt), benzene-1,2-dithiol (bdt), and toluene-3,4-dithiol (tdt) with potentially tridentate P,P,P-ligands bis(2-diphenylphosphino-ethyl) phenylphosphine (triphosI) and 1,1,1-tris-(diphenylphosphino-methyl)-ethane (triphosII) of the [Ni(P, P, P)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical, and conductivity measurements. Single-crystal X-ray analysis of [Ni(triphosI)(mnt)] confirmed a planar geometry of NiP2S2 chromophore (one of P-atoms is not coordinated). Possible practical applications such as the use of these compounds as anticholinesterase agents were evaluated.
  • A series of Ni(II) dithiolenes derived from maleonitriledithiol (mnt), benzene-1,2-dithiol (bdt), and toluene-3,4-dithiol (tdt) with potentially tridentate P,P,P-ligands bis(2-diphenylphosphino-ethyl) phenylphosphine (triphosI) and 1,1,1-tris-(diphenylphosphino-methyl)-ethane (triphosII) of the [Ni(P, P, P)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical, and conductivity measurements. Single-crystal X-ray analysis of [Ni(triphosI)(mnt)] confirmed a planar geometry of NiP2S2 chromophore (one of P-atoms is not coordinated). Possible practical applications such as the use of these compounds as anticholinesterase agents were evaluated. (en)
Title
  • Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands
  • Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands (en)
skos:prefLabel
  • Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands
  • Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands (en)
skos:notation
  • RIV/61989592:15310/12:33140878!RIV13-MSM-15310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, V, Z(MO0FVZ0000604)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 158799
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/12:33140878
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Inhibitor; Cholinesterase; X-ray structure; Dithiolenes; Nickel(II) (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [5EC933487460]
http://linked.open...i/riv/nazevZdroje
  • Journal of Coordination Chemistry
http://linked.open...in/vavai/riv/obor
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 65
http://linked.open...iv/tvurceVysledku
  • Pohanka, Miroslav
  • Kameníček, Jiří
  • Dlhan, Lubor
  • Herich, Peter
  • Holas, Ondrej
  • Kozisek, Jozef
  • Kuca, Kamil
http://linked.open...ain/vavai/riv/wos
  • 000302034300014
http://linked.open...n/vavai/riv/zamer
issn
  • 0095-8972
number of pages
http://bibframe.org/vocab/doi
  • 10.1080/00958972.2011.644543
http://localhost/t...ganizacniJednotka
  • 15310
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