About: Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands     Goto   Sponge   NotDistinct   Permalink

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  • A series of planar Ni(II) dithiolenes derived from maleonitriledithiole (mnt), benzene-1,2-dithiole (bdt) and 1-toluene-3,4-dithiole (tdt) with bidentate N,N-ligands (bpy = 2,2'-bipyridine; phen = 1,10-phenanthroline; nphen = 5-nitro-1,10-phenanthroline) of the [Ni(N,N)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(phen)(bdt)] confirmed a planar geometry of NiN2S2. Possible practical applications such as use for vulcanization catalytic agents and for their anticholinesterase activity were evaluated.
  • A series of planar Ni(II) dithiolenes derived from maleonitriledithiole (mnt), benzene-1,2-dithiole (bdt) and 1-toluene-3,4-dithiole (tdt) with bidentate N,N-ligands (bpy = 2,2'-bipyridine; phen = 1,10-phenanthroline; nphen = 5-nitro-1,10-phenanthroline) of the [Ni(N,N)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(phen)(bdt)] confirmed a planar geometry of NiN2S2. Possible practical applications such as use for vulcanization catalytic agents and for their anticholinesterase activity were evaluated. (en)
Title
  • Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands
  • Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands (en)
skos:prefLabel
  • Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands
  • Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands (en)
skos:notation
  • RIV/61989592:15310/08:00009945!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ME 865), S
http://linked.open...iv/cisloPeriodika
  • 22
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 386729
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/08:00009945
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Nickel(II); N,S-ligands; Vulcanization agents; Cholinesterase; Inhibitor. (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [077838892AF2]
http://linked.open...i/riv/nazevZdroje
  • Journal of Coordination Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 61
http://linked.open...iv/tvurceVysledku
  • Kuča, Kamil
  • Jun, Daniel
  • Olšovský, Milan
  • Kameníček, Jiří
  • Herich, Peter
issn
  • 0095-8972
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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