About: Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex

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About: Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A water-soluble complex fullerene and .gamma.-cyclodextrin [C60(.gamma.CD)2] mediates an electrocatalytic conversion of dinitrogen to ammonia. The EIS data obtained under the atmosphere of argon or nitrogen were analyzed. A decrease of the charge-transfer resistance in the presence of nitrogen was found and used for selection of the most efficient potential for the electrochemical nitrogen fixation. Optimization was verified by the preparative electrolysis and detection of ammonia. A water-soluble complex fullerene and .gamma.-cyclodextrin [C60(.gamma.CD)2] mediates an electrocatalytic conversion of dinitrogen to ammonia. The EIS data obtained under the atmosphere of argon or nitrogen were analyzed. A decrease of the charge-transfer resistance in the presence of nitrogen was found and used for selection of the most efficient potential for the electrochemical nitrogen fixation. Optimization was verified by the preparative electrolysis and detection of ammonia. (en) Ve vodě rozpustný komplex fulerenu a .gamma.–cyklodextrinu [C60(.gamma.CD)2] zprostředkovává elektrokatalytickou konverzi dusíku na amoniak. Byla provedena analýza EIS pod atmosférou argonu a dusíku. Zjištěný pokles odporu přenosu náboje v přítomnosti dusíku byl využit pro výběr nejúčinnějšího potenciálu pro elektrochemickou fixaci dusíku. Za optimálních podmínek byla provedena preparativní elektrolýza a detekován amoniak. (cs)
Title	Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex (en) Elektrochemická impedance fixace dusíku v přítomnosti komplexu fuleren-cyklodextrin (cs)
skos:prefLabel	Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex (en) Elektrochemická impedance fixace dusíku v přítomnosti komplexu fuleren-cyklodextrin (cs)
skos:notation	RIV/61388955:_____/08:00310223!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA400400505), P(KJB400400603), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	25
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Pospíšil, Lubomír Sokolová, Romana Hromadová, Magdaléna Gál, Miroslav Bulíčková, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	365777
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/08:00310223
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	impedance; nitrogen fixation; fullerene-cyclodextrin complex; ammonia (en)
http://linked.open.../riv/klicoveSlovo	ammonia impedance nitrogen fixation fullerene-cyclodextrin complex
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[D206BDAC3940]
http://linked.open...i/riv/nazevZdroje	Electrochimica acta
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Redox reactions of free radicals, reactivity in presence of host molecules Redox reactions of cyclooxygenase-2 inhibitors and their reactive intermediates in supramolecular nanocavities
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	53
http://linked.open...iv/tvurceVysledku	Gál, Miroslav Hromadová, Magdaléna Pospíšil, Lubomír Sokolová, Romana Fanelli, N. Bulíčková, Jana
http://linked.open...ain/vavai/riv/wos	000259015300012
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0013-4686
number of pages	6 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex

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